IrI(η4-diene) precatalyst activation by strong bases: formation of an anionic IrIII tetrahydride.
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DOI: 10.1039/d2dt04036k
Abstract: The reaction between [IrCl(COD)]2 and dppe in a 1 : 2 ratio was investigated in detail under three different conditions. [IrCl(COD)(dppe)], 1, is formed at room temperature in the absence of base. In the presence of a… read more here.
Keywords: ircl cod; iriii; tetrahydride; dppe ... See more keywords