Thianthrenation-Enabled Pyrrolidin-2-yl and Tetrahydrofuran-2-yl Methylation of (Hetero)Arenes.
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DOI: 10.1021/acs.orglett.3c00582
Abstract: The mild and efficient palladium-catalyzed pyrrolidin-2-yl and tetrahydrofuran-2-yl methylation of (hetero)arenes has been developed. A wide range of (hetero)arenes underwent the regioselective thianthrenation to generate the arylthianthrenium triflate, and the developed Pd-catalyzed alkene carboamination and… read more here.
Keywords: methylation hetero; tetrahydrofuran; tetrahydrofuran methylation; hetero arenes ... See more keywords