Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes
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DOI: 10.1021/acs.organomet.8b00557
Abstract: Although previous studies of the stabilization of Ln(II) ions across the lanthanide series have relied on Me3Si-substituted cyclopentadienyl ligands, we now find surprisingly that these ions can also exist surrounded by three tetramethylcyclopentadienyl ligands. Reduction… read more here.
Keywords: across lanthanide; tetramethylcyclopentadienyl ligands; ions across; lanthanide series ... See more keywords