A linear tetranuclear Cu(II) complex exhibiting both ferro and antiferromagnetic couplings: Synthesis, characterization and magneto-structural studies
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.03.006
Abstract: Abstract The pyrimidinyl hydrazone ligand O C{NHN C(Me)(pm)}2 (pm = 2-pyrimidinyl) (L3H2) has two potentially protic H atoms and multiple donor atoms. The reaction of L3H2 with CuCl2·2H2O yielded the tetranuclear complex [Cu4(L3H)2Cl6(CH3OH)2] (1). Structural studies on… read more here.
Keywords: linear tetranuclear; donor set; tetranuclear complex; centre ... See more keywords
Norbornadiene as a Building Block for the Synthesis of Linked Benzazocinones and Benzazocinium Salts through Tetranuclear Carbopalladated Intermediates
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DOI: 10.1021/acs.organomet.6b00795
Abstract: The six-membered C,N-palladacycle [Pd(C,N-C6H4CH2CMe2NH2-2)(μ-Cl)]2 (A) derived from phentermine reacts with norbornadiene to give a di- or tetranuclear complex arising from the double insertion of the same molecule of the strained alkene into one or two… read more here.
Keywords: norbornadiene building; tetranuclear complex; geometry; benzazocinones benzazocinium ... See more keywords