Luminescent Di- and Tetranuclear Gold Complexes of Bis(diphenylphosphinyl)-Functionalized Dipyrido-Annulated N-Heterocyclic Carbene.
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DOI: 10.1021/acs.inorgchem.9b00514
Abstract: Phosphine-functionalized N-heterocyclic carbene (NHC) ligands are known to complex group 11 metal centers to form multinuclear complexes with photoluminescence properties. This study reports a structurally rigid ortho-substituted dipyrido-annulated NHC with T-shape coordination geometry and its… read more here.
Keywords: metal; dipyrido annulated; tetranuclear gold; gold complexes ... See more keywords
Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4-Symmetric Tetratriazol-5-ylidene
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DOI: 10.1021/acs.organomet.7b00712
Abstract: The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits… read more here.
Keywords: synthesis catalytic; catalytic benefits; benefits tetranuclear; tetranuclear gold ... See more keywords
The first representatives of tetranuclear gold(i) complexes of P,N-containing cyclophanes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01073k
Abstract: The first representatives of the tetranuclear gold(i) complexes of P,N-containing cyclophanes with two 1,5-diaza-3,7-diphosphacyclooctane rings incorporated into the macrocyclic core have been obtained. The complexation leads to a change in ligand conformations so that the… read more here.
Keywords: first representatives; tetranuclear gold; gold; representatives tetranuclear ... See more keywords