H-bond assisted coordination bond formation in the 1D chains based on azido and phenoxido bridged tetranuclear Cu(II) complexes with reduced Schiff base ligands
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DOI: 10.1016/j.poly.2017.12.022
Abstract: Abstract Two new 1D chains [(CuL1R)2Cu2(N3)2(μ1,1,3-N3)2]n (1) and [{(CuL2R)2Cu2(N3)2(μ1,1,3-N3)2}·(CH3)2CO]n (2) based on rare μ1,1,3-N3 bridged tetranuclear Cu(II) complexes, have been synthesized using [CuL1R] and [CuL2R] as “metalloligands” [where H2L1R = N,N′-bis(2-hydroxybenzyl)-1,3-propanediamine and H2L2R = N,N′-bis(2-hydroxybenzyl)-1,2-ethylenediamine]. Both complexes have been… read more here.
Keywords: bond; tetranuclear complexes; bridged tetranuclear; tetranuclear ... See more keywords