Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki-Miyaura Coupling.
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DOI: 10.1021/jacs.7b05071
Abstract: A highly stereocontrolled synthesis of tetrasubstituted acyclic all-carbon olefins has been developed via a stereoselective enolization and tosylate formation, followed by a palladium-catalyzed Suzuki-Miyaura cross-coupling of the tosylates and pinacol boronic esters in the presence… read more here.
Keywords: synthesis tetrasubstituted; miyaura coupling; tetrasubstituted acyclic; suzuki miyaura ... See more keywords