Constructing Full-Color Highly Emissive Organic Solids Based on an X-Shaped Tetrasubstituted Benzene Skeleton
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b01251
Abstract: With the aim of highlighting the potential talent of the unique single-benzene skeleton versus the common large π-systems, we propose a general strategy to construct single-benzene fluorophores 1–9, featuring fascinating emission properties in the solid… read more here.
Keywords: tetrasubstituted benzene; shaped tetrasubstituted; single benzene; benzene ... See more keywords
Aerobic Oxidative N-Heterocyclic Carbene-Catalyzed Formal [3+3] Cyclization for the Synthesis of Tetrasubstituted Benzene Derivatives
Sign Up to like & getrecommendations! Published in 2022 at "Organic Letters"
DOI: 10.1021/acs.orglett.2c03879
Abstract: Herein, we present an accessible aerobic N-heterocyclic carbene (NHC)-catalyzed method that efficiently produces tetrasubstituted benzene rings in a single reaction. The method employs atmospheric oxygen (O2) as the terminal oxidant in a reaction that requires… read more here.
Keywords: aerobic oxidative; carbene catalyzed; heterocyclic carbene; tetrasubstituted benzene ... See more keywords