Isomerization of N-Allyl Amides To Form Geometrically Defined Di-, Tri-, and Tetrasubstituted Enamides.
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DOI: 10.1021/jacs.7b00564
Abstract: Enamides represent bioactive pharmacophores in various natural products, and have become increasingly common reagents for asymmetric incorporation of nitrogen functionality. Yet the synthesis of the requisite geometrically defined enamides remains problematic, especially for highly substituted… read more here.
Keywords: amides form; allyl amides; isomerization; tri tetrasubstituted ... See more keywords