Functional 1,2,4,5‐Tetrazine Systems for Photocatalysis and Sensing
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400553
Abstract: s‐Tetrazines are aromatic heterocyclic systems with distinct structural and optoelectronic features, which have led to the design and development of tetrazine‐derived systems in various applications. In this review, we summarize all the research reported on the subject… read more here.
Keywords: chemistry; tetrazine systems; systems photocatalysis; tetrazine ... See more keywords
Bioorthogonal Postlabeling Reveals Nuclear Localization of a Highly Cytotoxic Half‐Sandwich Ir(III) Tetrazine Complex in Live Cells
Sign Up to like & getrecommendations! Published in 2025 at "Chembiochem"
DOI: 10.1002/cbic.202500090
Abstract: Intracellular imaging of anticancer metallodrugs often relies on prelabeling with organic fluorophores, which significantly affects their physicochemical properties and intracellular distribution. On the other hand, the reported postlabeling strategies based on click‐chemistry reactions require cell… read more here.
Keywords: half; highly cytotoxic; sandwich iii; tetrazine ... See more keywords
Assessment of the effect of N-oxide group in a new high-performance energetic tetrazine derivative on its physicochemical and thermodynamic properties, sensitivity, and combustion and detonation performance
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-017-2126-5
Abstract: This work uses density functional theory and suitable predictive methods to assess the effect of N-oxide group in 1,2-bis(6-nitro-1,2,4,5-tetrazin-3-yl)diazene 1-oxide as a new heterocycle-based high performance tetrazine explosive and its thermophysical and performance properties. Important… read more here.
Keywords: effect oxide; sensitivity; tetrazine; detonation ... See more keywords
Structural, spectral and theoretical study of the coordination of 3,6-bis(2-pyridyl)tetrazine ligand with zinc(II) and mercury(II)
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.08.023
Abstract: Abstract We report the synthesis and single crystal X-ray structures of three zinc(II) and mercury(II) coordination polymers (1D-zigzag-{[Zn(μ-BPTZ)Cl2]·DMSO}n (1), 1D-zigzag-{[Zn(μ-BPTZ)Br2]·CH3CN}n (2) and 2D-herringbone [Hg2(μ-BPTZ)(μ-CN)2(CN)2]n (3)) and a binuclear 3D-supramolecular coordination compound of mercury(II), [Hg2(μ-BPTZ)(SCN)4] (4),… read more here.
Keywords: coordination; zinc mercury; tetrazine; bptz ... See more keywords
Synthesis, characterization and self-assembly of new cholesteryl-substitued sym-tetrazine: Fluorescence, gelation and mesogenic properties
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2021.117543
Abstract: Abstract Fluorescent liquid crystalline organogels have been considered as proper candidates for low-energy consumption electronic displays particularly for portable flexible electronics. Herein, we synthesized novel fluorescent symmetric 3,6-bis(4-(cholesterylester)phenyl)-1,2,4,5-tetrazine (sym-Tetrazine; DCh-Tz) liquid crystalline low molecular weight… read more here.
Keywords: gelation; self assembly; cholesterylester tetrazine; sym tetrazine ... See more keywords
Electrochemical studies of novel thiophene-tetrazine donor-acceptor hybrids
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2021.152905
Abstract: Abstract The compartmentalization of molecular properties is achievable in thiophene-tetrazine assemblies featuring non-conjugating spacer-groups between electron rich thiophene rings and electron deficient s-tetrazine rings. The assemblies have been studied electrochemically and spectro-electrochemically and our results… read more here.
Keywords: tetrazine; thiophene tetrazine; electrochemical studies; novel thiophene ... See more keywords
Red Light Activation of Tetrazine–Norbornene Conjugation for Bioorthogonal Polymer Cross-Linking across Tissue
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.7b00561
Abstract: Light-triggered chemistry has been used extensively in polymer cross-linking for the preparation of hydrogels. However, most photoclick reactions rely on the use of UV light that is easily absorbed by and damaging to cells and… read more here.
Keywords: chemistry; tetrazine; cross linking; activation ... See more keywords
Triazine Chalcogenones from Thiocyanate or Selenocyanate Addition to Tetrazine Ligands in Ruthenium Arene Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00459
Abstract: The chemistry of 1,2,4,5-tetrazines has attracted considerable interest both from a synthetic and applicative standpoint. Recently, regioselective reactions with alkynes and alkenes have been reported to be favored once the tetrazine ring is coordinated to… read more here.
Keywords: thiocyanate selenocyanate; addition; chemistry; triazine ... See more keywords
Clip to Click: Controlling Inverse Electron-Demand Diels-Alder Reactions with Macrocyclic Tetrazines.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01010
Abstract: A universal strategy to control tetrazine reactivity in the inverse electron-demand Diels-Alder (IEDDA) reaction was developed as "Clip to Click". Incorporating a chemical bridge into 3,6-diphenyl-1,2,4,5-tetrazine (macrocyclic tetrazine) rendered it unreactive toward trans-cyclooctene. A computational… read more here.
Keywords: tetrazine; electron demand; demand diels; inverse electron ... See more keywords
Investigation of Proteome-Tetrazine Reactivity for a Highly Selective Tetrazine Ligation in Live Cells
Sign Up to like & getrecommendations! Published in 2025 at "ACS Central Science"
DOI: 10.1021/acscentsci.5c00525
Abstract: Tetrazine has been widely used in bio-orthogonal click chemistry for diverse biological applications due to its short reaction time and excellent bio-orthogonality. For efficient click reaction, the stability of tetrazine in physiological conditions is one… read more here.
Keywords: chemistry; tetrazine derivatives; tetrazine; live cells ... See more keywords
Fluorogenic NIR-probes based on 1,2,4,5-tetrazine substituted BF2-azadipyrromethenes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06545k
Abstract: A series of 1,2,4,5-tetrazine integrated near infrared (NIR) fluorophores based on the BF2 azadipyrromethene (NIR-AZA) class has been synthesised and their ability to modulate emission from low to high in response to Diels-Alder cycloaditions has… read more here.
Keywords: fluorogenic nir; probes based; based tetrazine; nir ... See more keywords