Assessment of the effect of N-oxide group in a new high-performance energetic tetrazine derivative on its physicochemical and thermodynamic properties, sensitivity, and combustion and detonation performance
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-017-2126-5
Abstract: This work uses density functional theory and suitable predictive methods to assess the effect of N-oxide group in 1,2-bis(6-nitro-1,2,4,5-tetrazin-3-yl)diazene 1-oxide as a new heterocycle-based high performance tetrazine explosive and its thermophysical and performance properties. Important… read more here.
Keywords: effect oxide; sensitivity; tetrazine; detonation ... See more keywords
Structural, spectral and theoretical study of the coordination of 3,6-bis(2-pyridyl)tetrazine ligand with zinc(II) and mercury(II)
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.08.023
Abstract: Abstract We report the synthesis and single crystal X-ray structures of three zinc(II) and mercury(II) coordination polymers (1D-zigzag-{[Zn(μ-BPTZ)Cl2]·DMSO}n (1), 1D-zigzag-{[Zn(μ-BPTZ)Br2]·CH3CN}n (2) and 2D-herringbone [Hg2(μ-BPTZ)(μ-CN)2(CN)2]n (3)) and a binuclear 3D-supramolecular coordination compound of mercury(II), [Hg2(μ-BPTZ)(SCN)4] (4),… read more here.
Keywords: coordination; zinc mercury; tetrazine; bptz ... See more keywords
Synthesis, characterization and self-assembly of new cholesteryl-substitued sym-tetrazine: Fluorescence, gelation and mesogenic properties
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2021.117543
Abstract: Abstract Fluorescent liquid crystalline organogels have been considered as proper candidates for low-energy consumption electronic displays particularly for portable flexible electronics. Herein, we synthesized novel fluorescent symmetric 3,6-bis(4-(cholesterylester)phenyl)-1,2,4,5-tetrazine (sym-Tetrazine; DCh-Tz) liquid crystalline low molecular weight… read more here.
Keywords: gelation; self assembly; cholesterylester tetrazine; sym tetrazine ... See more keywords
Electrochemical studies of novel thiophene-tetrazine donor-acceptor hybrids
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2021.152905
Abstract: Abstract The compartmentalization of molecular properties is achievable in thiophene-tetrazine assemblies featuring non-conjugating spacer-groups between electron rich thiophene rings and electron deficient s-tetrazine rings. The assemblies have been studied electrochemically and spectro-electrochemically and our results… read more here.
Keywords: tetrazine; thiophene tetrazine; electrochemical studies; novel thiophene ... See more keywords
Red Light Activation of Tetrazine–Norbornene Conjugation for Bioorthogonal Polymer Cross-Linking across Tissue
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.7b00561
Abstract: Light-triggered chemistry has been used extensively in polymer cross-linking for the preparation of hydrogels. However, most photoclick reactions rely on the use of UV light that is easily absorbed by and damaging to cells and… read more here.
Keywords: chemistry; tetrazine; cross linking; activation ... See more keywords
Triazine Chalcogenones from Thiocyanate or Selenocyanate Addition to Tetrazine Ligands in Ruthenium Arene Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00459
Abstract: The chemistry of 1,2,4,5-tetrazines has attracted considerable interest both from a synthetic and applicative standpoint. Recently, regioselective reactions with alkynes and alkenes have been reported to be favored once the tetrazine ring is coordinated to… read more here.
Keywords: thiocyanate selenocyanate; addition; chemistry; triazine ... See more keywords
Clip to Click: Controlling Inverse Electron-Demand Diels-Alder Reactions with Macrocyclic Tetrazines.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01010
Abstract: A universal strategy to control tetrazine reactivity in the inverse electron-demand Diels-Alder (IEDDA) reaction was developed as "Clip to Click". Incorporating a chemical bridge into 3,6-diphenyl-1,2,4,5-tetrazine (macrocyclic tetrazine) rendered it unreactive toward trans-cyclooctene. A computational… read more here.
Keywords: tetrazine; electron demand; demand diels; inverse electron ... See more keywords
Fluorogenic NIR-probes based on 1,2,4,5-tetrazine substituted BF2-azadipyrromethenes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06545k
Abstract: A series of 1,2,4,5-tetrazine integrated near infrared (NIR) fluorophores based on the BF2 azadipyrromethene (NIR-AZA) class has been synthesised and their ability to modulate emission from low to high in response to Diels-Alder cycloaditions has… read more here.
Keywords: fluorogenic nir; probes based; based tetrazine; nir ... See more keywords
Preparation of tetrazine-containing [2 + 1] complexes of 99mTc and in vivo targeting using bioorthogonal inverse electron demand Diels-Alder chemistry.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01497j
Abstract: The aim of this work was to synthesize and evaluate [2 + 1] 99mTc(i) polypyridine complexes containing tetrazines, which along with the corresponding Re(i) complexes, represent a new class of isostructural nuclear and turn-on luminescent… read more here.
Keywords: complexes 99mtc; vivo; chemistry; tetrazine ... See more keywords
Tetrazine-induced activation of a trimethyl lock as a click-to-release system for protected doxorubicin.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01334k
Abstract: We herein report a novel chemically triggered click-to-release system, that combines the trimethyl lock (TML) lactonization with the bioorthogonal inverse electron demand Diels-Alder (IEDDA) reaction of a vinyl ether and a tetrazine. Kinetic studies were… read more here.
Keywords: system; click release; release system; tetrazine ... See more keywords
Evaluation of a 68Ga-Labeled DOTA-Tetrazine as a PET Alternative to 111In-SPECT Pretargeted Imaging
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25030463
Abstract: The bioorthogonal reaction between a tetrazine and strained trans-cyclooctene (TCO) has garnered success in pretargeted imaging. This reaction was first validated in nuclear imaging using an 111In-labeled 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTA)-linked bispyridyl tetrazine (Tz) ([111In]In-DOTA-PEG11-Tz) and… read more here.
Keywords: dota peg11; 68ga labeled; dota; tetrazine ... See more keywords