Tetrazine-Based Ligand Transformation Driving Metal–Metal Bond and Mixed-Valence HgI/HgII
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DOI: 10.1021/acsomega.8b01861
Abstract: Understanding the self-assembly of cluster aggregates remains an important challenge in coordination chemistry. A chelating tetrazine-based ligand was employed to isolate an unprecedented tetranuclear Hg4 complex exhibiting HgI/HgII mixed valence, which also contains metal–metal bonds.… read more here.
Keywords: tetrazine based; metal; based ligand; mixed valence ... See more keywords