1,3,5-Tris[(2H-tetrazol-5-yl)methyl]isocyanurate and Its Tricationic Salts as Thermostable and Insensitive Energetic Materials.
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DOI: 10.1021/acs.orglett.2c01225
Abstract: Various energetic salts (3a-f) were obtained from 1,3,5-tris[(2H-tetrazol-5-yl)methyl]isocyanurate (3), while N2,N4,N6-tri(1H-tetrazol-5-yl)-1,3,5-triazine-2,4,6-triamine (5) and N,N'-{6-[(1H-tetrazol-5-yl)amino]-1,3,5-triazine-2,4-diyl}bis[N-(1H-tetrazol-5-yl)nitramide] (6) were obtained from cyanuric chloride via a simple, efficient two-step synthetic route from inexpensive starting materials. Compounds 3a-f and 6… read more here.
Keywords: tris tetrazol; tetrazol methyl; isocyanurate tricationic; methyl isocyanurate ... See more keywords
Crystal structures of the three closely related compounds: bis[(1H-tetrazol-5-yl)methyl]nitramide, triaminoguanidinium 5-({[(1H-tetrazol-5-yl)methyl](nitro)amino}methyl)tetrazol-1-ide, and diammonium bis[(tetrazol-1-id-5-yl)methyl]nitramide monohydrate
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DOI: 10.1107/s2056989017008817
Abstract: The crystal packing and intermolecular hydrogen-bonding schemes vary greatly between the three compounds. In all three structures, the nitramide is mainly sp 2-hybridized and the bond lengths indicate delocalization of charges on the tetrazole rings. read more here.
Keywords: tetrazol methyl; methyl nitramide; methyl; crystal structures ... See more keywords