Contribution of Nonaxial n → σ* Orbital Interactions in Tetrel Bonding: A Case Study on Si…N Interactions
Sign Up to like & getrecommendations! Published in 2025 at "Chemphyschem"
DOI: 10.1002/cphc.202500042
Abstract: The formation of a σ‐hole interaction is typically associated with a corresponding n → σ* orbital interaction. This study examines the role of these n → σ* interactions in stabilizing Si…N tetrel bonding within various dimeric complexes. While conventional… read more here.
Keywords: contribution nonaxial; nonaxial orbital; interactions tetrel; tetrel bonding ... See more keywords
Tetrel bonding on graphene
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.11.011
Abstract: Abstract Many experimental detections and theoretical calculations have shown that the small molecules CO2, N2, CO, H2O and NH3 can be adsorbed on the graphene-family nanomaterials. The molecule CO2 can form tetrel bonds with N2,… read more here.
Keywords: co2; tetrel bonding; graphene tetrel; bonding graphene ... See more keywords
Computational Study of Driving Forces in ATSP, PDIQ, and P53 Peptide Binding: C=O···C=O Tetrel Bonding Interactions at Work
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Chemical Information and Modeling"
DOI: 10.1021/acs.jcim.3c00024
Abstract: Understanding the molecular interactions that drive peptide folding is crucial to chemistry and biology. In this study, we analyzed the role of CO···CO tetrel bonding (TtB) interactions in the folding mechanism of three different peptides… read more here.
Keywords: chemistry; biology; atsp pdiq; tetrel bonding ... See more keywords
Extended lead(II) architectures engineered via tetrel bonding interactions
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00525g
Abstract: The evaluation of N′-(pyridin-2-ylmethylene)nicotinohydrazide (HLI) and N,N′′′-bis(1-(pyridin-2-yl)-ethylidene)carbazide (H2LII) as linker precursors in the synthesis of novel PbII extended structures is described. An equimolar one-pot reaction of PbX2 (X = NO3−, CH3COO−) salts with HLI and… read more here.
Keywords: extended lead; lead architectures; engineered via; architectures engineered ... See more keywords
On the importance of RH3C⋯N tetrel bonding interactions in the solid state of a dinuclear zinc complex with a tetradentate Schiff base ligand
Sign Up to like & getrecommendations! Published in 2021 at "CrystEngComm"
DOI: 10.1039/d0ce01864c
Abstract: The tetrel bonding and π-stacking interactions in a new dinuclear zinc complex using a tetradentate N2O2 donor Schiff base have been analysed energetically using DFT calculations and several computational tools. read more here.
Keywords: schiff base; tetrel bonding; zinc complex; dinuclear zinc ... See more keywords
The importance of tetrel bonding interactions with carbon in two arrestive iso-structural Cd(ii)–Salen coordination complexes: a comprehensive DFT overview in crystal engineering
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DOI: 10.1039/d2ra07080d
Abstract: In this article, we describe the serendipitous synthesis of two remarkable iso-structural Cd(ii)–Salen complexes [L2Cd4(OAc)2(NCS)2] in the presence of H2L and NaSCN {where L = L1 (N,N′-bis(3-methoxysalicylidene)-1,2-diaminopropane) and L = L2 (N,N′-bis(3-methoxysalicylidene)-ethylenediamine) in 1 and… read more here.
Keywords: iso structural; geometry; structural salen; tetrel bonding ... See more keywords
Differential Binding of Tetrel-Bonding Bipodal Receptors to Monatomic and Polyatomic Anions
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24020227
Abstract: Previous work has demonstrated that a bidentate receptor containing a pair of Sn atoms can engage in very strong interactions with halide ions via tetrel bonds. The question that is addressed here concerns the possibility… read more here.
Keywords: tetrel; differential binding; binding tetrel; tetrel bonding ... See more keywords