The influence of tetrel bonds on the acidities of group 14 tetrafluoride ‐ inorganic acid complexes
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26822
Abstract: Ab initio methods were used to determine the influence of tetrel bond formation on the acidity. The systems composed of inorganic acids and tetrafluorides of 14 group elements have been tested ‐ HA/EF4, where HA… read more here.
Keywords: group; tetrel bonds; bonds acidities; tetrel ... See more keywords
Comparison for Electron Donor Capability of Carbon-Bound Halogens in Tetrel Bonds
Sign Up to like & getrecommendations! Published in 2021 at "ACS Omega"
DOI: 10.1021/acsomega.1c04085
Abstract: The tetrel bond formed by HC≡CX, H2C=CHX, and H3CCH2X (X=F, Cl, Br, I) as an electron donor and TH3F (T=C, Si, Ge) was explored by ab initio calculations. The tetrel bond formed by H3CCH2X is… read more here.
Keywords: tetrel bonds; electron donor; comparison electron; bond ... See more keywords
Synthesis, spectroscopic findings and crystal engineering of Pb(ii)–Salen coordination polymers, and supramolecular architectures engineered by σ-hole/spodium/tetrel bonds: a combined experimental and theoretical investigation
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d1ra09346k
Abstract: Spontaneous self-assembly is one of the available synthetic routes to achieve structurally versatile and unique crystal complexes with selected metal–ligand combinations in the spirit of pseudohalides. In this endeavour, we designed a novel 1D coordination… read more here.
Keywords: spectroscopic findings; coordination; tetrel bonds; spodium tetrel ... See more keywords
On the Power of Geometry over Tetrel Bonds
Sign Up to like & getrecommendations! Published in 2018 at "Molecules"
DOI: 10.3390/molecules23112742
Abstract: Tetrel bonds are noncovalent interactions formed by tetrel atoms (as σ-hole carriers) with a Lewis base. Here, we present a computational and molecular orbital study on the effect of the geometry of the substituents around… read more here.
Keywords: tetrel bonds; tetrel; geometry; geometry tetrel ... See more keywords