Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me4N][XCF3] (X = S, Se) and TfOH
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DOI: 10.3390/molecules25194535
Abstract: The first Markovnikov-type hydrotrifluoromethylselenolation of unactivated terminal alkenes with the readily accessible [Me4N][SeCF3] reagent and the superacid TfOH is reported. The reaction proceeded at room temperature under catalyst- and additive-free conditions to give the branched… read more here.
Keywords: markovnikov type; tfoh; type hydrotrifluoromethylchalcogenation; unactivated terminal ... See more keywords