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Published in 2020 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.151576
Abstract: Abstract We developed an efficient method for synthesis of tetrafunctionalized 2-imidazolines using TfOH-catalyzed formal [3+2] cycloaddition of N-tosylaziridine dicarboxylates and nitriles. This is the first report of C–N bond cleavage of N-tosylaziridine dicarboxylates catalyzed by…
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Keywords:
tosylaziridine dicarboxylates;
tfoh catalyzed;
synthesis tetrafunctionalized;
tetrafunctionalized imidazolines ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05676c
Abstract: Selective alkylation of 2-pyridone could solve a challenge in chemistry and streamline the synthesis of important molecules. Here we report the regioselective O-alkylation of 2-pyridones by TfOH-catalyzed carbenoid insertion. In the catalytic system, alkylation of…
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Keywords:
catalyzed carbenoid;
tfoh catalyzed;
alkylation pyridones;
alkylation ... See more keywords