ThC2@C82versus Th@C84: unexpected formation of triangular thorium carbide cluster inside fullerenes
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DOI: 10.1039/d2sc04846a
Abstract: Synthesis of the first thorium-containing clusterfullerenes, ThC2@Cs(6)–C82 and ThC2@C2(5)–C82, is reported. These two novel actinide fullerene compounds were characterized by mass spectrometry, single-crystal X-ray diffraction crystallography, UV–vis–NIR spectroscopy, and theoretical calculations. Crystallographic studies reveal that… read more here.
Keywords: 600 40z; 600 600; thorium; c84 unexpected ... See more keywords