Isolable endocyclic silenes by thermal Brook rearrangement
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DOI: 10.1016/j.jorganchem.2016.12.019
Abstract: Abstract In the following study, we investigated thermally and photolytically induced transformations of acylcyclotetrasilanes (Me3Si)2Si4Me8(Me3Si)COR (compounds 9a-c; R = alkyl, aryl). Mild thermolysis of 9a-c below 130 °C cleanly and selectively afforded the corresponding endocyclic silenes 10b-d irrespective… read more here.
Keywords: thermal brook; silenes thermal; endocyclic silenes; brook rearrangement ... See more keywords