Kinetics and mechanism for thermal and photochemical decomposition of 4,4′-azobis(4-cyanopentanoic acid) in aqueous media
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DOI: 10.1039/c9py00507b
Abstract: The two diastereoisomers of 4,4′-azobis(4-cyanopentanoic acid) decompose at different rates in aqueous media. The major products (>50%) are amides produced by trapping the ketenimines formed by C–N coupling. read more here.
Keywords: kinetics mechanism; cyanopentanoic acid; aqueous media; azobis cyanopentanoic ... See more keywords
Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions.
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DOI: 10.1039/d3cc00328k
Abstract: Commercially available Co2(CO)8 was used as an effective catalyst for the hydrosilylation of nitroarenes under both thermal and photochemical conditions. A wide variety of nitroarenes with various functionalities were selectively reduced to aromatic amines. Syntheses… read more here.
Keywords: cobalt catalyzed; catalyzed chemoselective; hydrosilylation; chemoselective reduction ... See more keywords
Thermal and Photochemical Stability Studies of Color-Converted MicroLED Microdisplay Panels
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DOI: 10.1109/jphot.2023.3281571
Abstract: The thermal and photochemical stabilities of colloidal quantum-dot (QD) nanophosphors incorporated into a blue microLED matrix by spin-cast deposition were investigated in this study. The optical characteristics of QDs-based color-converted microLEDs were also investigated in… read more here.
Keywords: microdisplay panels; photochemical stability; color converted; thermal photochemical ... See more keywords