Kinetics of Thermal Polymerization Can Be Studied during Continuous Cooling.
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201700624
Abstract: It is demonstrated that differential scanning calorimetry can measure the kinetics of the thermally initiated polymerization during continuous cooling. The measurements are accomplished by switching from fast heating to much slower cooling. The study is… read more here.
Keywords: polymerization; continuous cooling; polymerization studied; kinetics thermal ... See more keywords
A metal-catalyzed thermal polymerization strategy toward atomically dispersed catalysts.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc05975j
Abstract: We report a general metal-catalyzed thermal polymerization strategy for the preparation of atomically dispersed catalysts that consist of isolated metal atoms (Fe, Co and Ni) hosted by a polymer-like carrier containing phenanthroline substructure. The prepared… read more here.
Keywords: catalyzed thermal; atomically dispersed; polymerization strategy; dispersed catalysts ... See more keywords
One-step thermal polymerization synthesis of nitrogen-rich g-C3N4 nanosheets enhances photocatalytic redox activity
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DOI: 10.1039/d2ra05867g
Abstract: Graphitic carbon nitride (g-C3N4) has attracted enormous attention as a visible-light-responsive carbon-based semiconductor photocatalyst. However, fast charge recombination seriously limits its application. Therefore, it is urgent to modify the electronic structure of g-C3N4 to obtain… read more here.
Keywords: polymerization synthesis; one step; synthesis nitrogen; thermal polymerization ... See more keywords
High Thermal Resistance of Epoxy/Cyanate Ester Hybrids Incorporating an Inorganic Double-Decker-Shaped Polyhedral Silsesquioxane Nanomaterial
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DOI: 10.3390/molecules27185938
Abstract: In this study, we prepared a difunctionalized cyanate ester double-decker silsesquioxane (DDSQ-OCN) cage with a char yield and thermal decomposition temperature (Td) which were both much higher than those of a typical bisphenol A dicyanate… read more here.
Keywords: double decker; cyanate ester; ddsq ocn; thermal polymerization ... See more keywords
Metal Complexes of the Porphyrin-Functionalized Polybenzoxazine
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DOI: 10.3390/polym14030449
Abstract: New porphyrin-functionalized benzoxazine (Por-BZ) in high purity and yield was synthesized in this study based on 1H and 13C NMR and FTIR spectroscopic analyses through the reduction of Schiff base formed from tetrakis(4-aminophenyl)porphyrin (TAPP) and… read more here.
Keywords: porphyrin functionalized; metal complexes; thermal polymerization; por ... See more keywords