SYNTHESIS AND STABILITY OF THERMALLY LABILE 1,2-OXAPHOSPHETANE 2-OXIDES AND 1,2-THIAPHOSPHETANE 2-SULFIDES
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DOI: 10.1007/5780
Abstract: Synthesis and thermal stability of 1,2-oxaphosphetane 2-oxide and 1,2-thiaphosphetane 2-sulfide derivatives are discussed. This microreview covers the available synthetic methods of thermally labile 1,2-oxaphosphetane 2-oxides and 1,2-thiaphosphetane 2-sulfides and their fragmentation. The synthetic approaches may… read more here.
Keywords: oxides thiaphosphetane; thiaphosphetane sulfides; oxaphosphetane oxides; oxaphosphetane ... See more keywords
Thermally labile mono-alkyl phosphates and their alkali metal derivatives: synthesis and solid-state supramolecular aggregation.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt00255a
Abstract: New organic-soluble mono-alkyl phosphate esters [(RO)P(O)(OH)2] have been synthesized by esterification of phosphoric acid with the corresponding aliphatic alcohols in the presence of acetic anhydride. The products were initially isolated as cyclohexylamine salts, viz. [CyNH3]2[(CF3CH2O)PO3]·H2O… read more here.
Keywords: mono alkyl; alkali metal; thermally labile; metal ... See more keywords