Silver(I)-Organic Frameworks Showing Remarkable Thermo-, Solvato- And Vapochromic Phosphorescence As Well As Reversible Solvent-Driven 3D-to-0D Transformations.
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DOI: 10.1021/acs.inorgchem.1c00480
Abstract: A series of isoreticular Ag(I) luminescent metal-organic frameworks (LMOFs), {[Ag2L2(CH3CN)2](X)2}n (X = ClO4, OTf, and BF4), has been designed, exploiting diphenyl(2-pyrazyl)phosphine (L) as a multidentate linker. At ambient temperature, these compounds emit a bright long-lived… read more here.
Keywords: thermo solvato; organic frameworks; solvato; solvent driven ... See more keywords