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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00009
Abstract: An acidity- and temperature-dependent chemoselective glycosylation of silyl-protected rhamnals with alcohols has been revealed. The reaction undergoes a 1,2-addition pathway with (±)-CSA as the catalyst at rt, affording kinetically controlled 2-deoxyl rhamnosides. In contrast, only…
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Keywords:
ferrier rearrangement;
temperature;
silyl protected;
thermodynamically controlled ... See more keywords
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Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc03449b
Abstract: The synthesis of two pairs of enantiomeric cyano-luminogens 1 and 2, in which the central chromophore is a p-phenylene or a 2,5-dithienylbenzene moiety, respectively, is described and their supramolecular polymerization under kinetic and thermodynamic control…
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Keywords:
aggregation;
cyano luminogens;
supramolecular polymerization;
thermodynamically controlled ... See more keywords