Thermoanalytical and NMR investigation of NaBH4 × 2H2O thermolysis process
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Thermal Analysis and Calorimetry"
DOI: 10.1007/s10973-017-6953-5
Abstract: The article describes the thermolysis process of sodium borohydride dihydrate in thermoanalytical experiments. The reaction was carried out without solid catalyst and with catalyst as cobalt boride Co2B. It has been found out that in… read more here.
Keywords: thermoanalytical nmr; thermolysis process; solid catalyst; process ... See more keywords
Effects of atmospheres on sulfur release and its transformation behavior during coal thermolysis
Sign Up to like & getrecommendations! Published in 2018 at "Fuel"
DOI: 10.1016/j.fuel.2017.11.099
Abstract: Abstract In this study, Pinshuo (PS) coal with high organic sulfur content was selected to investigate the effects of atmospheres on sulfur release and its transformation during thermolysis. Pyrolysis connected with gas chromatography (Py-GC) was… read more here.
Keywords: atmospheres sulfur; transformation; co2; thermolysis ... See more keywords
1,3-Dichloro-1,1,2,2,3,3-hexa- tert -butyltristannane: Thermolysis involving trapping of stannylene, t Bu 2 Sn: and reactivity with various nucleophiles
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.03.045
Abstract: Abstract The bifunctional 1,3-dichloro-tristannane CltBu2Sn-SntBu2-SntBu2Cl, 1, has been investigated with respect to thermolysis and nucleophilic substitution. Thermolysis of 1 leads to slow elimination of the stannylene which may be trapped by elemental sulphur, PhSSPh and… read more here.
Keywords: tert butyltristannane; hexa tert; dichloro hexa; butyltristannane thermolysis ... See more keywords
Suppression of forest fuel thermolysis by water mist
Sign Up to like & getrecommendations! Published in 2018 at "International Journal of Heat and Mass Transfer"
DOI: 10.1016/j.ijheatmasstransfer.2018.05.085
Abstract: Abstract The processes involved in the suppression of thermolysis in typical forest fuel (mixtures of birch leaves, asp branches, spruce needles) have been experimentally researched. The suppression was achieved by exposing forest fuel (FF) to… read more here.
Keywords: forest fuel; suppression; water; thermolysis ... See more keywords
Mechanistic and kinetic study of thermolysis reaction with hydrolysis step products in Cu–Cl thermochemical cycle
Sign Up to like & getrecommendations! Published in 2021 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2021.01.118
Abstract: Abstract Copper–Chlorine cycle has been identified as the most prospective among the low temperature thermochemical cycles for hydrogen production. The cycle consists of two thermal reaction steps, one electrochemical step and a physical separation step.… read more here.
Keywords: cycle; hydrolysis step; thermolysis; step ... See more keywords
Catalytic thermolysis of oak sawdust using Fe-based catalyst and CO2
Sign Up to like & getrecommendations! Published in 2019 at "Journal of CO2 Utilization"
DOI: 10.1016/j.jcou.2019.04.024
Abstract: Abstract To achieve the more sustainable thermolytic energy conversion platform for biomass, this study particularly employed CO2 as reactive gas medium. Thus, this study laid great emphasis on elucidating the mechanistic role of CO2 during… read more here.
Keywords: co2; catalyst; thermolysis; study ... See more keywords
Coupling Postsynthetic High-Temperature Oxidative Thermolysis and Thermal Rearrangements in Isoreticular Zinc MOFs.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03334
Abstract: Herein, we report coupling in situ high temperature postsynthetic modifications (PSMs) in metal-organic frameworks (MOFs). Thermo-reactive propargyloxy-functionalized zinc IRMOFs (isoreticular metal-organic frameworks) prepared from 2-(prop-2-yn-1-yloxy)-[1,1'-biphenyl]-4,4'-dicarboxylic acid (H2bpdcOCH2CCH) were investigated for their high-temperature postsynthetic rearrangement (PSR)… read more here.
Keywords: chemistry; mofs; high temperature; zinc ... See more keywords
Fabrication of a WS2/p-Si heterostructure photocathode using direct hybrid thermolysis.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b08654
Abstract: P-N heterostructures based on TMDs and a conventional semiconductor, such as p-Si, have been considered a promising structure for next-generation electronic devices and applications. However, synthesis of high-quality, wafer-scale TMDs, particularly WS2 on p-Si, is… read more here.
Keywords: fabrication ws2; thermolysis; photocathode; hybrid thermolysis ... See more keywords
Variation of heavy oil composition during thermolysis with the addition of kerosene fraction of hydrocracking in flow reactor
Sign Up to like & getrecommendations! Published in 2018 at "Petroleum Science and Technology"
DOI: 10.1080/10916466.2018.1542446
Abstract: Abstract Thermolysis experiments of heavy oil have been carried out in flow reactor with the addition of 2.5–5.0% kerosene fraction of hydrocracking of vacuum gas oil prepared from conventional oil. It has been shown that… read more here.
Keywords: kerosene fraction; thermolysis; heavy oil; flow reactor ... See more keywords
Group Composition of Hydrocarbons and Hetero Compounds in Stepwise-Thermolysis Products of Asphaltenes from Usa Oil
Sign Up to like & getrecommendations! Published in 2018 at "Petroleum Chemistry"
DOI: 10.1134/s096554411803012x
Abstract: The group composition of hydrocarbons (HC) and hetero compounds in the products of stepwise thermolysis of asphaltenes from crude oil of the Usa oilfield at temperatures of 120, 230, 370, 500 and 750°C has been… read more here.
Keywords: hydrocarbons hetero; composition hydrocarbons; group composition; hetero compounds ... See more keywords
Structural Transformations of Petroleum Resins and Their Fractions by Thermolysis
Sign Up to like & getrecommendations! Published in 2018 at "Petroleum Chemistry"
DOI: 10.1134/s0965544118080078
Abstract: Resins of Usa oil and their four fractions obtained by column chromatography have been studied. Changes in the structural parameters of the resins and the product composition for thermolysis of the fractions at temperatures of… read more here.
Keywords: thermolysis; transformations petroleum; petroleum resins; resins fractions ... See more keywords