Thermoregulated phase-separable rhodium nanoparticle catalyst for selective hydrogenation of α,β-unsaturated aldehydes and ketones
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DOI: 10.1039/c7ra10351d
Abstract: Thermoregulated phase-separable Rh nanoparticles (abbreviated as TPS-Rhnano) were found to be efficient catalysts for selective hydrogenation of CC bonds in α,β-unsaturated aldehydes and ketones with a selectivity of >99% at >99% conversion. More importantly, the… read more here.
Keywords: unsaturated aldehydes; phase; thermoregulated phase; selective hydrogenation ... See more keywords
A novel thermoregulated phase-transfer catalysis system for chiral nano-Pt-catalyzed asymmetric hydrogenation
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Chemical Research"
DOI: 10.1177/17475198211039133
Abstract: The chiral ionic liquid CILTPT-MS [CH3(OCH2CH2)16CD]+[CH3SO3]− (CD = cinchonidine) is found to exhibit cloud point character. Due to this cloud point character, a CILTPT-MS-stabilized chiral nano-Pt catalyst is prepared and utilized to realize transfer in a H2O–1-pentanol… read more here.
Keywords: system; thermoregulated phase; phase transfer; transfer catalysis ... See more keywords