Articles with "thf" as a keyword



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Performances of Several Solvents on the Cleavage of Inter- and Intramolecular Linkages of Lignin in Corncob Residue.

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Published in 2018 at "ChemSusChem"

DOI: 10.1002/cssc.201800309

Abstract: The performances of solvents, including γ-butyrolactone (GBL), γ-valerolactone (GVL), tetrahydrofuran (THF), ethyl acetate (EAC), 2-methyltetrahydrofuran (2-MeTHF), and the corresponding mixtures with H2 O, on the cleavage of inter- and intramolecular linkages of lignin in corncob… read more here.

Keywords: thf; lignin corncob; intramolecular linkages; cleavage inter ... See more keywords
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Pentamethylcyclopentadienyl‐Supported Cerocene(III) Complexes

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Published in 2017 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.201601404

Abstract: The trivalent ate complex Cp*2CeCl2K(thf) (Cp* = C5Me5) was used in a diverse set of salt metathesis reactions. Equimolar reactions with LiNiPr2, LiN(SiHMe2)2, KN(SiMe3)2, and LiCH2C6H4-o-NMe2 gave the alkali metal-free complexes Cp*2Ce(NiPr2), Cp*2Ce[N(SiHMe2)2], Cp*2Ce[N(SiMe3)2], and… read more here.

Keywords: 2ce ctbu; thf; iii complexes; supported cerocene ... See more keywords
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Multinuclear compounds of s-elements with sterically hindered о-semiquinonates and catecholates

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Published in 2018 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-018-2038-2

Abstract: Alkali metals form mutinuclear compounds with redox-active singly and doubly reduced derivatives of sterically of hindered о-benzoquinones. Complexes [Na6(Cat)3(THF)7]•4THF, [Na5(Cat)2(SQ)(THF)5], [Na4(SQ)4(THF)4]•THF•C6H14, [Na4(3,5-SQ)4(THF)4], [K4(SQ)4(THF)4]•4THF and [Li3(SQ)3(THF)3]•THF (Cat is catecholate, SQ is semiquinonate) possessing high sensitivity to… read more here.

Keywords: elements sterically; thf thf; sterically hindered; thf ... See more keywords
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Synthesis and structure of manganese(ii) coordination polymers with 1,4-diazabicyclo[2.2.2]octane N, N′-dioxide: solvent and template effects

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Published in 2020 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-020-2930-4

Abstract: New metal-organic frameworks [Mn(DMF)2(odabco)2](ClO4)2 · H2O (1), [Mn(H2O)2− (HCOO)2] · odabco (2), and [Mn(Hodabco)2(odabco)3](NO3)4 (3) were synthesized by the reaction of manganese Perchlorate with 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco) in N, N-dimethylformamide (DMF) under varying reaction conditions.… read more here.

Keywords: diazabicyclo octane; coordination; thf; dmf ... See more keywords
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Thermodynamic and kinetic modelling of mixed CH4-THF hydrate for methane storage application

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Published in 2019 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2019.03.172

Abstract: Abstract Solidified natural gas (SNG) is a promising solution to long standing NG storage problem. NG hydrate formation is the most significant step in the application of SNG technology. For improving the hydrate forming conditions,… read more here.

Keywords: ch4 thf; thf; thf hydrate; model ... See more keywords

Superior Mg2+ storage properties of VS2 nanosheets by using an APC-PP14Cl/THF electrolyte

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Published in 2019 at "Energy Storage Materials"

DOI: 10.1016/j.ensm.2019.04.004

Abstract: Abstract The difficult Mg2+ desolvation of chloride-based electrolytes and slow Mg2+ diffusion in the cathode seriously hinder the electrochemical performance of Mg-ion batteries (MIBs). To solve these problems, a high performance MIB cell was built… read more here.

Keywords: mg2 desolvation; mg2; pp14cl; thf ... See more keywords
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Sodium Dodecyl Sulfate Preferentially Promotes Enclathration of Methane in Mixed Methane-Tetrahydrofuran Hydrates

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Published in 2019 at "iScience"

DOI: 10.1016/j.isci.2019.03.020

Abstract: Summary Methane storage in mixed hydrates is advantageous due to faster kinetics and added stability. However, capacity needs to be improved. Here we study mixed hydrates of methane (CH4) and tetrahydrofuran (THF), in the presence… read more here.

Keywords: dodecyl sulfate; thf; methane; sodium dodecyl ... See more keywords
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TMPMg n Bu(L), where L = THF, 2-MeTHF, pyridine and dimethylaminopyridine and TMP = 1,5,9-trimesityldipyrromethene: Reaction with lactide and ε -caprolactone

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Published in 2017 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2017.05.016

Abstract: Abstract The compounds TMPMgnBu(L), where L = THF, 2-MeTHF, pyridine (py) and dimethylaminopyridine (DMAP) and TMP = 1,5,9-trimesityldipyrromethene, have been synthesized and allowed to initiate polymerization with rac-lactide (rac-LA) and e-caprolactone (e – CL). Both the rate of rac-LA… read more here.

Keywords: methf pyridine; thf methf; thf; pyridine dimethylaminopyridine ... See more keywords
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Holocene paleoearthquakes on the Tianqiaogou-Huangyangchuan fault in the northeastern boundary fault system of the Tibetan Plateau

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Published in 2019 at "Journal of Asian Earth Sciences"

DOI: 10.1016/j.jseaes.2019.104049

Abstract: Abstract Rupture behavior, one of the quantitative features of active fault, is fundamental for understanding crustal deformation mechanisms and assessing regional seismic risk. The 120-km-long Tianqiaogou-Huangyangchuan Fault (THF) is an important branch fault of the… read more here.

Keywords: fault; huangyangchuan fault; thf; fault system ... See more keywords
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Biogas purification via sII hydrates in the presence of THF and DMSO solutions using MD simulations

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Published in 2020 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2019.111904

Abstract: Abstract Biogas is the result of the biological degradation of organic waste and consists mainly of a mixture of different gases, including CH4 and CO2. Both gases, if they could be separated from the mixture,… read more here.

Keywords: sii hydrates; thf; ch4; biogas ... See more keywords
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Synthesis and Characterization of Pyridine Dipyrrolide Uranyl Complexes

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Published in 2022 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.2c00348

Abstract: The first actinide complexes of the pyridine dipyrrolide (PDP) ligand class, (MesPDPPh)UO2(THF) and (Cl2PhPDPPh)UO2(THF), are reported as the UVI uranyl adducts of the bulky aryl substituted pincers (MesPDPPh)2– and (Cl2PhPDPPh)2– (derived from 2,6-bis(5-(2,4,6-trimethylphenyl)-3-phenyl-1H-pyrrol-2-yl)pyridine (H2MesPDPPh, Mes… read more here.

Keywords: thf; pyridine dipyrrolide; pyridine; uo2 thf ... See more keywords