Enantioselective Au‐Catalyzed Synthesis of Thia[5]‐ and Thia[6]helicenes and Their Transformation into Bowl‐shaped Pleiadenes
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202211279
Abstract: A series of helically shaped benzo[b]chryseno[4,3‐d]thiophenes, naphtho[1,2‐b]phenanthro[4,3‐d]thiophenes, and chryseno[3,4‐b]naphtho[1,2‐d]thiophenes is synthesized via a highly enantioselective Au‐catalyzed intramolecular alkyne hydroarylation reaction. The inversion barriers of the structures obtained are determined both theoretically and experimentally, and their… read more here.
Keywords: enantioselective catalyzed; thia; catalyzed synthesis; transformation ... See more keywords
Degradation of thiacloprid via unactivated peroxymonosulfate: The overlooked singlet oxygen oxidation
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.124264
Abstract: Abstract Unactivated peroxymonosulfate (PMS) degrading organic contaminants has been reported. Previous studies have focused on direct PMS oxidation, while the role of singlet oxygen (1O2) is often overlooked. Here, we studied the oxidation of thiacloprid… read more here.
Keywords: oxygen; degradation; pms; oxidation ... See more keywords
Synthesis and evaluation of novel 1,4,7-triazacyclononane derivatives as Cu2+ and Ga3+ chelators.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2022.111719
Abstract: Advances in chelator design are the cornerstone for the development of metals like copper and gallium based biomedical agents and radiopharmaceuticals. To develop optimal chelating ligands, we explored the synthesis and chelating properties of azaheterocycle… read more here.
Keywords: thia; noda thia; acid; noda ... See more keywords
A RETROSPECTIVE COMPARISON OF CHEMICAL IMMOBILIZATION WITH THIAFENTANIL, THIAFENTANIL-AZAPERONE, OR ETORPHINE-ACEPROMAZINE IN CAPTIVE PERSIAN FALLOW DEER (DAMA DAMA MESOPOTAMICA)
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Zoo and Wildlife Medicine"
DOI: 10.1638/2016-0280.1
Abstract: Abstract Records of 56 Persian fallow deer (Dama dama mesopotamica) immobilized for translocation were reviewed. Twenty-three were administered 0.05 ± 0.01 (mean ± SD) mg/kg thiafentanil (THIA), 20 were administered 0.045 ± 0.008 mg/kg thiafentanil… read more here.
Keywords: deer; dama; immobilization; thia ... See more keywords