Oxidative Dearomatization of PLP in Thiamin Pyrimidine Biosynthesis in Candida albicans.
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DOI: 10.1021/jacs.2c08560
Abstract: The yeast thiamin pyrimidine synthase THI5p catalyzes one of the most complex organic rearrangements found in primary metabolism. In this reaction, the active site His66 and PLP are converted to thiamin pyrimidine in the presence… read more here.
Keywords: dearomatization plp; oxidative dearomatization; plp thiamin; thiamin pyrimidine ... See more keywords