Exploration of SMM behavior of Ln2 complexes derived from thianaphthene-2-carboxylic acid.
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DOI: 10.1039/c9dt01984g
Abstract: Two lanthanide-based dinuclear complexes [LnIII(L)3(DMF)(H2O)]2 (Ln = DyIII (1)/TbIII (2)) derived from thianaphthene-2-carboxylic acid have been synthesized and characterized in detail. Single-crystal XRD analyses confirm that the centro-symmetric discrete dimeric structures contain eight-coordinated lanthanide centers… read more here.
Keywords: smm behavior; carboxylic acid; derived thianaphthene; exploration smm ... See more keywords