Diverse Synthesis of (Thio)ethers and (Thio)esters Using Halodiborylmethane as a Transformable C1 Building Block.
Sign Up to like & getrecommendations! Published in 2024 at "Organic letters"
DOI: 10.1021/acs.orglett.4c02510
Abstract: The development of effective strategies to forge C-O and C-S bonds in diverse chemical spaces is of considerable interest in synthetic organic chemistry. Herein we report a versatile approach for the modular synthesis of structurally… read more here.
Keywords: thio ethers; halodiborylmethane; thio esters; ethers thio ... See more keywords
Iron-catalyzed selective hydrodeoxygenation and hydrodesulfurization of (thio)esters by hydrosilylation under blue light activation for access to (thio)ethers
Sign Up to like & getrecommendations! Published in 2026 at "Chemical Communications"
DOI: 10.1039/d5cc06110e
Abstract: The iron-catalyzed hydrodeoxygenation of S-alkyl thioesters and esters and desulfurisation of O-alkyl thioate derivatives using hydrosilane, leading to (thio)ethers, is described. A wide range of thioesters and esters gave the corresponding unsymmetrical thioethers and ethers… read more here.
Keywords: thio ethers; thio; hydrodeoxygenation; hydrodeoxygenation hydrodesulfurization ... See more keywords
Synthesis and Antioxidant Activity of New Catechol Thioethers with the Methylene Linker
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27103169
Abstract: Novel catechol thio-ethers with different heterocyclic substituents at sulfur atom were prepared by reacting 3,5-di-tert-butyl-6-methoxymethylcatechol with functionalized thiols under acidic conditions. A common feature of compounds is a methylene bridge between the catechol ring and… read more here.
Keywords: thio ethers; synthesis antioxidant; catechol thioethers; activity ... See more keywords