Articles with "thioester" as a keyword



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Characterization of a thioester-containing protein from the pearl oyster Pinctada fucata and its role in phagocytosis

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Published in 2021 at "Aquaculture Reports"

DOI: 10.1016/j.aqrep.2021.100833

Abstract: Abstract Thioester-containing proteins (TEPs) superfamily is known to play important innate immune functions in vertebrates and invertebrates, and involved in recognition, and killing of invading pathogens. Here, a TEP gene (designated as Pf-TEP) was obtained… read more here.

Keywords: protein; tep; thioester containing; pearl oyster ... See more keywords
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Semiaromatic Poly(thioester) from the Copolymerization of Phthalic Thioanhydride and Epoxide: Synthesis, Structure, and Properties

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Published in 2019 at "Macromolecules"

DOI: 10.1021/acs.macromol.9b00073

Abstract: We report a new semiaromatic poly(thioester) obtained through the copolymerization of phthalic thioanhydride and propylene oxide. The reaction was catalyzed by a chromium-based complex in conjunction with [PPN]Cl, where PPN = bis(triphenylphosphine)iminium. The reaction temperature… read more here.

Keywords: thioester; phthalic thioanhydride; poly thioester; semiaromatic poly ... See more keywords
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Structure of the Reductase Domain of a Fungal Carboxylic Acid Reductase and Its Substrate Scope in Thioester and Aldehyde Reduction

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Published in 2022 at "ACS Catalysis"

DOI: 10.1021/acscatal.2c04426

Abstract: The synthesis of aldehydes from carboxylic acids has long been a challenge in chemistry. In contrast to the harsh chemically driven reduction, enzymes such as carboxylic acid reductases (CARs) are considered appealing biocatalysts for aldehyde… read more here.

Keywords: carboxylic acid; structure; domain; thioester ... See more keywords
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Understanding and Circumventing the Requirement for Native Thioester Substrates for α-Oxoamine Synthase Reactions.

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Published in 2022 at "ACS chemical biology"

DOI: 10.1021/acschembio.2c00365

Abstract: Many enzyme classes require thioester electrophiles such as acyl-carrier proteins and acyl-coenzyme A substrates. For in vitro applications, these substrates can render these chemical transformations impractical. To address this challenge, we have investigated the mechanism… read more here.

Keywords: oxoamine synthase; understanding circumventing; native thioester; circumventing requirement ... See more keywords
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Investigation on thermal behaviour and optical properties of non-symmetric cholesterol-based twin liquid crystals with thioester linkages

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Published in 2020 at "Liquid Crystals"

DOI: 10.1080/02678292.2019.1706107

Abstract: ABSTRACT Herein, a series of novel asymmetric cholesterol-based liquid crystal compounds containing thioester linkage and an analogue containing carboxylate linking unit have been synthesised and characterised. Thermal analyses demonstrated that all desired target compounds possess… read more here.

Keywords: cholesterol based; liquid crystals; investigation thermal; thermal behaviour ... See more keywords