Hydrolyzable Poly(β-Thioether Ester Ketal) Thermosets via Acyclic Ketal Monomers.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200028
Abstract: Hydrolytically degradable poly(β-thioether ester ketal) thermosets are synthesized via radical-mediated thiol-ene photopolymerization using three novel dialkene acyclic ketal monomers and a mercaptopropionate based tetrafunctional thiol. For all thermoset compositions investigated, degradation behavior is highly tunable… read more here.
Keywords: acyclic ketal; ester ketal; thioether ester; thioether ... See more keywords
Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.126913
Abstract: Abstract Systematic synthesis of thioether-linked dimers and trimers was carried out to reveal molecular designs for inducing mesophases and twist-bend nematic (NTB) phases. A five-fold approach based on molecular structural parameters including the terminal substituent,… read more here.
Keywords: thioether; twist bend; dimers trimers; bend nematic ... See more keywords
Bioinformatic Mapping of Radical S-Adenosylmethionine-Dependent Ribosomally Synthesized and Post-Translationally Modified Peptides Identifies New Cα, Cβ, and Cγ-Linked Thioether-Containing Peptides.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b01519
Abstract: Recently developed bioinformatic tools have bolstered the discovery of ribosomally synthesized and post-translationally modified peptides (RiPPs). Using an improved version of Rapid ORF Description and Evaluation Online (RODEO 2.0), a biosynthetic gene cluster mining algorithm,… read more here.
Keywords: translationally modified; post translationally; thioether; ribosomally synthesized ... See more keywords
ROS-responsive poly(ε-caprolactone) with pendent thioether and selenide motifs
Sign Up to like & getrecommendations! Published in 2018 at "Polymer Chemistry"
DOI: 10.1039/c8py00620b
Abstract: The chalcogen-containing polyesters represent an important branch of reactive oxygen species (ROS)-responsive biodegradable polymers. Herein, we report the synthesis and oxidation properties of three ROS-responsive poly(e-caprolactone) (PCL)-type polyesters. Three new α-substituted caprolactone-type monomers: α-ethylthio caprolactone… read more here.
Keywords: thioether; caprolactone; responsive poly; poly caprolactone ... See more keywords
Synthesis of Silane-Based Poly(thioether) via Successive Click Reaction and Their Applications in Ion Detection and Cell Imaging
Sign Up to like & getrecommendations! Published in 2019 at "Polymers"
DOI: 10.3390/polym11081235
Abstract: A series of poly(thioether)s containing silicon atom with unconventional fluorescence were synthesized via successive thiol click reaction at room temperature. Although rigid π-conjugated structure did not exist in the polymer chain, the poly(thioether)s exhibited excellent… read more here.
Keywords: poly thioether; cell imaging; via successive; thioether ... See more keywords