Articles with "thioether carboranes" as a keyword



Photo by trnavskauni from unsplash

Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes

Sign Up to like & get
recommendations!
Published in 2017 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2017.09.004

Abstract: Abstract Two new dirhenium compounds Re2(CO)8[μ-η2-1,3-C2B10H10(1-SCH3)](μ-H), 1 (3.2 % yield) and Re2(CO)8[μ-η2-1,4-C2B10H10(1-SCH3)](μ-H), 2 (31 % yield) were obtained from the reaction of closo-o-(1-SCH3)C2B10H11 with Re2(CO)8[μ-η2-C(H)C(H)Bun](μ-H) in an octane solution heated to reflux. Both compounds contain… read more here.

Keywords: re2; thioether carboranes; chemistry; sch3 ... See more keywords