Synthesis of selenoether and thioether functionalized bicyclo[1.1.1]pentanes
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DOI: 10.1016/j.tet.2020.131692
Abstract: Abstract Bicyclo[1.1.1]pentane is widely recognized as the bioisostere for aryl, tert-butyl, and internal alkynes. Herein we report an efficient and practical method for the preparation of selenoether and thioether functionalized bicyclo[1.1.1]pentanes from selenosulfonates/thiosulfonates and propellane.… read more here.
Keywords: bicyclo pentanes; selenoether thioether; functionalized bicyclo; thioether functionalized ... See more keywords
Rh(I) Complexes with Hemilabile Thioether-Functionalized NHC Ligands as Catalysts for [2 + 2 + 2] Cycloaddition of 1,5-Bisallenes and Alkynes
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DOI: 10.1021/acscatal.2c05790
Abstract: The [2 + 2 + 2] cycloaddition of 1,5-bisallenes and alkynes under the catalysis of Rh(I) with hemilabile thioether-functionalized N-heterocyclic carbene ligands is described. This protocol effectively provides an entry to different trans-5,6-fused bicyclic systems… read more here.
Keywords: cycloaddition bisallenes; complexes hemilabile; hemilabile thioether; thioether functionalized ... See more keywords
Isolation and studies of a thioether-functionalized pyrazole derived Cu(i)-based cyclic trinuclear complex and its coordination polymers with [Cu2I2] and [BiBr3] nodes
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DOI: 10.1039/d1tc02829d
Abstract: Emissive Cu(i)-CTC with unprecedented thioether SBUs have their photoluminescence shifted and quenched after assembly with CuI and BiBr3, respectively. read more here.
Keywords: derived based; functionalized pyrazole; isolation studies; studies thioether ... See more keywords