Synthesis of Bicyclic P,S-Heterocycles via the Addition of Thioketones to a Phosphorus-Centered Open-Shell Singlet Biradical.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03207
Abstract: Formal addition reactions between the open-shell singlet biradical [P(μ-NTer)]2 (1Ter) and xanthione, thioxanthione, as well as ferrocenyl naphthyl thioketone were studied in detail. Reactions were performed at room temperature and led to the formation of… read more here.
Keywords: addition; shell singlet; thioketone; open shell ... See more keywords
Synthesis and photophysical properties of conjugated thioketone, thioketone S-oxide (Sulfine), and related compounds incorporated in a dibenzobarrelene skeleton
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Sulfur Chemistry"
DOI: 10.1080/17415993.2020.1727905
Abstract: ABSTRACT Conjugated thioketone and thioketone S-oxide (sulfine) were synthesized from the corresponding ketone conjugated to a 1,3-butadiene system incorporated in a dibenzobarrelene skeleton. The conjugated thioketone was obtained by the reaction of the corresponding diazo… read more here.
Keywords: thioketone thioketone; oxide sulfine; thioketone; incorporated dibenzobarrelene ... See more keywords