Biofunctional Polyacrylamide Hydrogels using Tetrazole‐Methylsulfone Comonomer for Thiol Conjugation
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.202301024
Abstract: Biofunctionalized polyacrylamide (PAAm) hydrogels are important 2D substrates for studying cell physics and mechanobiology. In this work, an arylmethylsulfone (MS) comonomer is developed that can be incorporated into PAAm gels under aqueous radical polymerization conditions.… read more here.
Keywords: thiol; paam hydrogels; conjugation; biofunctional polyacrylamide ... See more keywords
Development of Thiol‐Labile α‐Amino Protecting Groups for Efficient Solid‐Phase Peptide Synthesis
Sign Up to like & getrecommendations! Published in 2025 at "ChemBioChem"
DOI: 10.1002/cbic.202500236
Abstract: Recently, a thiol‐labile α‐amino‐protecting group, 2,4‐dinitro‐6‐phenyl‐benzenesulfenyl (DNPBS), is introduced for solid‐phase peptide synthesis (SPPS). DNPBS‐SPPS effectively mitigates major side reactions—such as aspartimide formation and α‐C racemization—that commonly occur in conventional Fmoc‐SPPS. However, N‐DNPBS‐protected histidine is… read more here.
Keywords: solid phase; thiol; spps; amino protecting ... See more keywords
Synthesis and Characterization of Thiol-Ene Networks Derived from Levoglucosenone.
Sign Up to like & getrecommendations! Published in 2024 at "ChemPlusChem"
DOI: 10.1002/cplu.202400383
Abstract: Levoglucosenone (LGO), a renewable compound obtained from cellulose biomass, has been utilized to prepare novel monomers bearing alkene functional groups. These monomer derivatives of LGO were subsequently cured via ultraviolet (UV)-initiated radical thiol-ene "click" chemistry… read more here.
Keywords: thiol; thiol ene; synthesis characterization; characterization thiol ... See more keywords
Mass Spectrometry-Based Method for Detection and Identification of Free Thiol Groups in Proteins.
Sign Up to like & getrecommendations! Published in 2019 at "Methods in molecular biology"
DOI: 10.1007/978-1-4939-9055-9_12
Abstract: Many proteins contain free sulfhydryl groups which can be involved in a variety of biochemical reactions. Reactive thiol groups can either reside within the active center of oxidoreductases or represent a part of a thiol-based… read more here.
Keywords: thiol; thiol groups; mass spectrometry; based method ... See more keywords
Exogenous melatonin regulates endogenous phytohormone homeostasis and thiol-mediated detoxification in two indica rice cultivars under arsenic stress
Sign Up to like & getrecommendations! Published in 2021 at "Plant Cell Reports"
DOI: 10.1007/s00299-021-02711-7
Abstract: Key message Melatonin enhanced arsenic (As) tolerance by inhibiting As bioaccumulation, modulating the expression of As transporters and phytohormone homeostasis, leading to efficient utilization of thiol machinery for sequestration and detoxification of this toxic metalloid.… read more here.
Keywords: thiol; phytohormone homeostasis; detoxification; expression ... See more keywords
Thiol/disulfide homeostasis in patients with ocular-active and ocular-inactive Behçet disease
Sign Up to like & getrecommendations! Published in 2020 at "International Ophthalmology"
DOI: 10.1007/s10792-020-01445-x
Abstract: Purpose To evaluate thiol/disulfide homeostasis in ocular-active (OA) and ocular-inactive (OI) Behçet disease (BD) patients and compare the data with healthy subjects. Methods Twenty OABD patients, 20 OIBD patients and 20 healthy control subjects were… read more here.
Keywords: thiol; disease; thiol disulfide; disulfide homeostasis ... See more keywords
In situ stabilization of some mercury-containing soils using organically modified montmorillonite loading by thiol-based material
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Soils and Sediments"
DOI: 10.1007/s11368-018-2150-9
Abstract: PurposeIn situ stabilization is a remediation technology that reduces the availability of mercury in contaminated soils by adding chemical substances. In this study, thiol-functionalized montmorillonite modified by organic surfactant (Mont-OR-SH) was used to stabilize soils… read more here.
Keywords: thiol; stabilization; situ stabilization; mercury containing ... See more keywords
Maternal Serum Levels of Zinc, Copper, and Thiols in Preeclampsia Patients: a Case-Control Study.
Sign Up to like & getrecommendations! Published in 2021 at "Biological trace element research"
DOI: 10.1007/s12011-021-02660-y
Abstract: Preeclampsia is one of the leading causes of maternal mortality-morbidity, and environmental factors act as the main driving force for the development of disease in genetically lean women. Trace element levels (zinc, copper) and thiol… read more here.
Keywords: thiol; zinc copper; copper; preeclampsia patients ... See more keywords
Dynamic thiol/disulphide homeostasis in children with Duchenne muscular dystrophy
Sign Up to like & getrecommendations! Published in 2018 at "Acta Neurologica Belgica"
DOI: 10.1007/s13760-018-01072-5
Abstract: Duchenne muscular dystrophy (DMD) is a disorder that alter the expression of the dystrophin protein. Dystrophin deficiency alters the structural integrity of the contractile apparatus/sarcolemmal integrity, leading to dystrophic changes. Dystrophin deficiency results in an… read more here.
Keywords: thiol; total thiol; native thiol; thiol disulphide ... See more keywords
Ratiometric quantitation of thiol metabolites using non-isotopic mass tags.
Sign Up to like & getrecommendations! Published in 2018 at "Analytica chimica acta"
DOI: 10.1016/j.aca.2018.02.057
Abstract: Ratiometric quantitation is used in mass spectrometry to account for variations in ionization efficiencies due to heterogenous sample matrixes. Isotopes are most commonly used to achieve ratiometric quantitation because of their ability to co-elute chromatographically… read more here.
Keywords: thiol; quantitation; mass; non isotopic ... See more keywords
Effects of humus on the mobility of arsenic in tailing soil and the thiol-modification of humus.
Sign Up to like & getrecommendations! Published in 2020 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2020.127403
Abstract: The ability of thiol-modified humic acids (HAs) to release arsenic in tailings soil after being modified with different sulfur-containing reagents were significantly improved. The structure and physicochemical properties of humic acid (HA) before and after… read more here.
Keywords: thiol; tailing soil; thiol modification; mobility arsenic ... See more keywords