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Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d1py00427a
Abstract: A photolatent transesterification catalyst is applied to locally switch on and control topological rearrangements in 3D printable thiol-acrylate vitrimers.
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Keywords:
locally controlling;
acrylate vitrimers;
controlling dynamic;
thiol acrylate ... See more keywords
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Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d1py00925g
Abstract: By following shape-memory assisted self-healing (SMASH), we used the shape-memory properties of thiol-acrylate photopolymers to physically close a scratch, whilst chemical healing was obtained via thermo-activated dynamic exchange reactions.
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Keywords:
thiol acrylate;
memory assisted;
shape memory;
assisted self ... See more keywords
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Published in 2022 at "Soft Matter"
DOI: 10.1039/d2sm00547f
Abstract: The Michael addition ‘click’ chemistry was used to graft acrylate-terminated mesogenic groups onto the polysiloxane backbone polymer chain with thiol functional groups, with a constant 15% fraction of diacrylate reacting monomers as crosslinkers. Three different…
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Keywords:
side chain;
acrylate side;
thiol acrylate;
layer ... See more keywords
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Published in 2022 at "Polymers"
DOI: 10.3390/polym14245377
Abstract: As an energy-efficient additive manufacturing process, vat photopolymerization 3D-printing has become a convenient technology to fabricate functional devices with high resolution and freedom in design. However, due to their permanently crosslinked network structure, photopolymers are…
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Keywords:
photopolymerization printing;
thiol acrylate;
vat photopolymerization;
acrylate ... See more keywords