Thiol dioxygenase turnover yields benzothiazole products from 2-mercaptoaniline and O2-dependent oxidation of primary alcohols.
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DOI: 10.1016/j.abb.2017.08.013
Abstract: Thiol dioxygenases are non-heme mononuclear iron enzymes that catalyze the O2-dependent oxidation of free thiols (-SH) to produce the corresponding sulfinic acid (-SO2-). Previous chemical rescue studies identified a putative FeIII-O2- intermediate that precedes substrate… read more here.
Keywords: thiol dioxygenase; dependent oxidation; oxidation; primary alcohols ... See more keywords