Thiol and H2S-Mediated NO Generation from Nitrate at Copper(II).
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DOI: 10.1021/jacs.3c00394
Abstract: Reduction of nitrate is an essential, yet challenging chemical task required to manage this relatively inert oxoanion in the environment and biology. We show that thiols, ubiquitous reductants in biology, convert nitrate to nitric oxide… read more here.
Keywords: thiol h2s; copper; biology; nitrate copper ... See more keywords