Click Step-Growth Polymerization and E/Z Stereochemistry Using Nucleophilic Thiol–yne/–ene Reactions: Applying Old Concepts for Practical Sustainable (Bio)Materials
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.2c00293
Abstract: Conspectus Polymer sustainability is synonymous with “bioderived polymers” and the zeitgeist of “using renewable feedstocks”. However, this sentiment does not adequately encompass the requirements of sustainability in polymers. In addition to recycling considerations and mechanical… read more here.
Keywords: step growth; stereochemistry; thiol yne; chemistry ... See more keywords
Shape Memory Behavior of Biocompatible Polyurethane Stereoelastomers Synthesized via Thiol-Yne Michael Addition.
Sign Up to like & getrecommendations! Published in 2022 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.1c01473
Abstract: Biodegradable shape memory elastomers have the potential for use in soft tissue engineering, drug delivery, and device fabrication applications. Unfortunately, few materials are able to meet the targeted degradation and mechanical properties needed for long-term… read more here.
Keywords: yne michael; addition; thiol yne; shape memory ... See more keywords
UV- and Visible-Light Photopatterning of Molecular Gradients Using the Thiol-yne Click Reaction.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c06946
Abstract: The rational design of chemical coatings is used to control surface interactions with small molecules, biomolecules, nanoparticles, and liquids as well as optical and other properties. Specifically, micropatterned surface coatings have been used in a… read more here.
Keywords: yne click; thiol yne; surface; click reaction ... See more keywords
Robust alginate/hyaluronic acid thiol-yne click-hydrogel scaffolds with superior mechanical performance and stability for load-bearing soft tissue engineering.
Sign Up to like & getrecommendations! Published in 2019 at "Biomaterials science"
DOI: 10.1039/c9bm01494b
Abstract: Hydrogels based on hyaluronic acid (HA) exhibit great potential as tissue engineering (TE) scaffolds as a consequence of their unique biological features. Herein, we examine how the advantages of two natural polymers (i.e. HA and… read more here.
Keywords: thiol yne; yne click; tissue; hyaluronic acid ... See more keywords
Synthesis of polymeric topological isomers based on sequential Ugi-4CR and thiol–yne click reactions with sequence-controlled amino-functionalized polymers
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/c9py01859j
Abstract: Herein, sequence-controlled polymerization and sequential Ugi-4CR/thiol–yne click reactions inspired a novel synthetic strategy for preparing a well-defined multigraft polymer in which the sequence-controlled amino-functionalized backbones were converted to mono- or di-modular alkynyl-functionalized main chains via… read more here.
Keywords: thiol yne; yne click; sequence controlled; polymer ... See more keywords
Thiol–yne crosslinked triarylamine hole transport layers for solution-processable organic light-emitting diodes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Materials Chemistry C"
DOI: 10.1039/d0tc03514a
Abstract: Formation of conjugated polymer thin-flim network by UV-triggered thiol–yne reaction of triarylamines and its use for hole transport in OLED. read more here.
Keywords: thiol yne; hole transport; triarylamine hole; yne crosslinked ... See more keywords
ESI-MS Analysis of Thiol-yne Click Reaction in Petroleum Medium
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26102896
Abstract: Petroleum contains a large number of heteroatomic compounds, but today, most of them are not efficiently utilized. The constant development of the sustainability concept recalls for rethinking the usage of fossil resources with improved chemical… read more here.
Keywords: analysis thiol; thiol yne; click reaction; reaction ... See more keywords