Synthesis and Reactivity of Thiolate‐Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP2S2 Metalloligand
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700937
Abstract: Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex into two different types of… read more here.
Keywords: thiolate bridged; niiimi heterodinuclear; heterodinuclear complexes; reactivity thiolate ... See more keywords
Construction and Reactivity of Benzimidazole‐Modified Thiolate‐Bridged Diiron Complexes with Different Electronic Structures
Sign Up to like & getrecommendations! Published in 2025 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400643
Abstract: Thiolate‐bridged diiron complexes have drawn extensive attention due to their wide applications in the biomimetic simulation for the structure and function of various metalloenzymes and the related bioinspired catalysis. Through the introduction of the functional… read more here.
Keywords: thiolate bridged; bridged diiron; thiolate; electronic structures ... See more keywords
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords
Reversible binding of dinitrogen on a thiolate-bridged cobalt-ruthenium complex supported by a flexible bidentate phosphine ligand.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01534j
Abstract: A well-defined thiolate-bridged cobalt-ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the… read more here.
Keywords: cobalt ruthenium; bridged cobalt; phosphine ligand; ruthenium complex ... See more keywords