Synthesis and Reactivity of Thiolate‐Bridged NiIIMI Heterodinuclear Complexes (M = Rh, Ir) with an S‐Bidentate NiP2S2 Metalloligand
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DOI: 10.1002/ejic.201700937
Abstract: Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of a low-valent dithiolate-bridged heterodinuclear complex into two different types of… read more here.
Keywords: thiolate bridged; niiimi heterodinuclear; heterodinuclear complexes; reactivity thiolate ... See more keywords
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
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DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords
Reversible binding of dinitrogen on a thiolate-bridged cobalt-ruthenium complex supported by a flexible bidentate phosphine ligand.
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DOI: 10.1039/d2dt01534j
Abstract: A well-defined thiolate-bridged cobalt-ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the… read more here.
Keywords: cobalt ruthenium; bridged cobalt; phosphine ligand; ruthenium complex ... See more keywords