Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex.
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DOI: 10.1021/acs.inorgchem.2c02383
Abstract: Addition of NO to a nonheme dithiolate-ligated iron(II) complex, FeII(Me3TACN)(S2SiMe2) (1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a metastable six-coordinate {FeNO}7 intermediate (S = 3/2) that was trapped at -135 °C… read more here.
Keywords: thiolate ligated; ligated iron; reduction n2o; iron complex ... See more keywords
Influence of Thiolate versus Alkoxide Ligands on the Stability of Crystallographically Characterized Mn(III)-Alkylperoxo Complexes.
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DOI: 10.1021/jacs.0c13001
Abstract: The work described herein demonstrates the exquisite control that the inner coordination sphere of metalloenzymes and transition-metal complexes can have on reactivity. We report one of few crystallographically characterized Mn-peroxo complexes and show that the… read more here.
Keywords: iii oor; thiolate ligated; crystallographically characterized; ligated iii ... See more keywords
Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds.
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DOI: 10.1021/jacs.1c07656
Abstract: Herein, we examine the electronic and geometric structural properties of O2-derived aliphatic thiolate-ligated Fe-peroxo, Fe-hydroxo, and Fe(IV) oxo compounds. The latter cleaves strong C-H bonds (96 kcal mol-1) on par with the valine C-H bond… read more here.
Keywords: thiolate ligated; thiolate; derived aliphatic; ligated peroxo ... See more keywords