Biallelic variants in CTU2 cause DREAM‐PL syndrome and impair thiolation of tRNA wobble U34
Sign Up to like & getrecommendations! Published in 2019 at "Human Mutation"
DOI: 10.1002/humu.23870
Abstract: The wobble position in the anticodon loop of transfer ribonucleic acid (tRNA) is subject to numerous posttranscriptional modifications. In particular, thiolation of the wobble uridine has been shown to play an important role in codon‐anticodon… read more here.
Keywords: dream; cause; wobble uridine; trna ... See more keywords
Study on the influence of thiolation on the adsorption and magnetic recovery of superparamagnetic nanoadsorbents for Cd 2+ removal
Sign Up to like & getrecommendations! Published in 2017 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2017.06.282
Abstract: Abstract In the study, the influence resulting from thiol-functionalization on Fe 3 O 4 -based superparamagnetic nanoadsorbents was investigated in detail, involving various physicochemical properties, especially, the contradiction between adsorption performance and magnetic recovery. The… read more here.
Keywords: adsorption; magnetic recovery; thiolation; study influence ... See more keywords
Oxidative stress induced S-thiolation by glutathione and homocysteine
Sign Up to like & getrecommendations! Published in 2018 at "Free Radical Biology and Medicine"
DOI: 10.1016/j.freeradbiomed.2018.10.027
Abstract: Although Vitamin C (AA, ascorbic acid; ascorbate ion at physiological pH) has multiple functions in humans its primary role is most likely as antioxidant thereby protecting the organism against continuously produced oxidative stress. When ascorbate… read more here.
Keywords: homocysteine; stress; dha; thiolation ... See more keywords
Investigation of tungstate thiolation reaction kinetics and sedimentary molybdenum/tungsten enrichments: Implication for tungsten speciation in sulfidic waters and possible applications for paleoredox studies
Sign Up to like & getrecommendations! Published in 2020 at "Geochimica et Cosmochimica Acta"
DOI: 10.1016/j.gca.2020.04.004
Abstract: Abstract The kinetics of tungstate (i.e., WO42−) thiolation were investigated in experimental solutions buffered at different pH values and as a function of varying dissolved sulfide concentrations. Similar to molybdate (MoO42−), tungstate undergoes stepwise thiolation… read more here.
Keywords: sulfidic environments; sulfidic waters; tungstate thiolation; partition coefficient ... See more keywords
Insight into copper-catalyzed decarboxylative thiolation of carboxylic acids in the gas phase
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.04.073
Abstract: Abstract Organocopper complexes bearing bidentate nitrogen ligands were synthesized in the gas phase by electrospray ionization mass spectrometry. Gas-phase decarboylative thiolation reaction was carried out in the ion-trap analyzer by collision-induced dissociation and ion-molecule reaction.… read more here.
Keywords: carboxylic acids; copper; gas; gas phase ... See more keywords
Cobalt-Catalyzed Direct C-H Thiolation of Aromatic Amides with Disulfides: Application to the Synthesis of Quetiapine.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b02812
Abstract: A direct C(sp2)-H thiolation of aromatic amides with disulfides was developed. The coupling reaction proceeds between the thioether radical and cobaltacycle intermediate. This method exhibits a relatively broad substrate scope and high functional group compatibility.… read more here.
Keywords: amides disulfides; aromatic amides; cobalt catalyzed; catalyzed direct ... See more keywords
Catalyst-free chemoselective α-sulfenylation/β-thiolation for α,β-unsaturated carbonyl compounds
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c9ra05708k
Abstract: This catalyst-free method provides a useful and efficient tool for the highly chemoselective preparation of α-thiolation or β-sulfenylation products of α,β-unsaturated carbonyl compounds. read more here.
Keywords: unsaturated carbonyl; carbonyl compounds; free chemoselective; sulfenylation ... See more keywords
Rhodium(iii)-catalyzed carboxylate-directed ortho-selective thiolation of benzoic acids
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00940g
Abstract: A regioselective rhodium-catalyzed carboxylate-directed thiolation process was developed. Several benzoic-acid derivatives and disulfides were found to be well-tolerated, and they yielded the corresponding products in moderate to good yields. Compounds such as the key precursor… read more here.
Keywords: iii catalyzed; catalyzed carboxylate; rhodium iii; carboxylate directed ... See more keywords
Pyridine hydrochloride-catalyzed thiolation of alkenes: divergent synthesis of allyl and vinyl sulfides
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo01052a
Abstract: A highly efficient and practical protocol for the synthesis of allylic and vinyl sulfides via pyridinium chloride-catalyzed tandem thiolation–elimination of alkenes is described. This tandem protocol offers easy access to both allylic and 1,1-diarylvinyl sulfides… read more here.
Keywords: vinyl sulfides; pyridine hydrochloride; hydrochloride catalyzed; synthesis ... See more keywords
Cp*Co(III)-catalyzed C2-thiolation and C2,C3-dithiolation of substituted indoles with N-(arylthio)succinimide.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc03760a
Abstract: A general and efficient Cp*CoIII-catalyzed C2-thiolation and C2,C3-dithiolation of indole derivatives has been achieved employing N-(aryl/alkylthio)succinimide as a thiolating reagent. This external oxidant-free method utilizes only catalytic amounts of additive and tolerates various functional groups… read more here.
Keywords: thiolation dithiolation; catalyzed thiolation; iii catalyzed; dithiolation substituted ... See more keywords
Visible-light-promoted C(sp3)-H thiolation of aliphatic ethers with thiosulfonates
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj01029e
Abstract: A visible-light-promoted direct thiolation of α-C(sp3)-H in ethers with thiosulfonates was developed for the preparation of α-arylthioethers using easily availably Na2-eosin Y and TBHP as photocatalyst and oxidant. This reaction... read more here.
Keywords: ethers thiosulfonates; light promoted; thiolation; promoted sp3 ... See more keywords