Latent Radical Cleavage of α-Allenylic C–O Bonds: Potassium Persulfate Mediated Thiolation of Allenylphosphine Oxides
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DOI: 10.1055/s-0037-1609835
Abstract: A novel potassium persulfate (K2S2O8) mediated thiolation of allenylphosphine oxides with diaryl sulfides is disclosed. Mechanistic studies indicate that K2S2O8 homolyzes the diaryl sulfide to produce a thiyl radical (PhS•), which is followed by C–O… read more here.
Keywords: thiolation allenylphosphine; mediated thiolation; allenylphosphine oxides; allenylphosphine ... See more keywords