Synthesis of an advanced intermediate enroute to thiomarinol antibiotics
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DOI: 10.1016/j.tet.2017.03.089
Abstract: Abstract A stereoselective synthesis of the C1-C14 fragment of thiomarinols is disclosed. The key steps include the stereoselective preparation of an allylic sulfide via a chloro sulfide by 1,2-asymmetric induction, ring-closing metathesis reaction, Kirmse-Doyle reaction… read more here.
Keywords: advanced intermediate; thiomarinol antibiotics; enroute thiomarinol; intermediate enroute ... See more keywords