Thionoesters: A Native Chemical Ligation-Inspired Approach to Cysteine-Triggered H2S Donors.
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DOI: 10.1021/jacs.8b07268
Abstract: Native chemical ligation (NCL) is a simple, widely used, and powerful synthetic tool to ligate N-terminal cysteine residues and C-terminal α-thioesters via a thermodynamically stable amide bond. Building on this well-established reactivity, as well as… read more here.
Keywords: native chemical; thionoesters native; cysteine; chemical ligation ... See more keywords