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   Articles with "thiosemicarbazone" as a keyword



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5-Nitrofuryl-Containing Thiosemicarbazone Gold(I) Compounds: Synthesis, Stability Studies, and Anticancer Activity.

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recommendations! Published in 2023 at "ChemPlusChem"

DOI: 10.1002/cplu.202300115

Abstract: This work describes the synthesis of four gold(I) [AuClL] compounds containing chloro and biologically active protonated thiosemicarbazones based on 5-nitrofuryl (L=HSTC). The stability of the compounds in dichloromethane, DMSO, and DMSO/culture media solutions was investigated… read more here.

Keywords: cell; stability; thiosemicarbazone; gold compounds ... See more keywords
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Synthesis, structural, cytotoxic and pharmacokinetic evaluation of some thiosemicarbazone derivatives.

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recommendations! Published in 2020 at "Journal of biochemical and molecular toxicology"

DOI: 10.1002/jbt.22512

Abstract: Iron(III) and nickel(II) complexes bearing a thiosemicarbazone framework were synthesized by a one-pot synthesis method. The structures were characterized by elemental analysis, IR, 1 H NMR, APCI Mass, conductivity, magnetic moment measurements. Molecular and crystal structures… read more here.

Keywords: pharmacokinetic evaluation; cytotoxic pharmacokinetic; synthesis structural; evaluation thiosemicarbazone ... See more keywords
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Natural products in crop protection: thiosemicarbazone derivatives of 3-acetyl-N-benzylindoles as antifungal agents and their mechanism of action.

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recommendations! Published in 2023 at "Pest management science"

DOI: 10.1002/ps.7457

Abstract: BACKGROUND Phytopathogenic fungi can cause a direct loss in economic value of agriculture. Especially Valsa mali Miyabe et Yamada, a devastating phytopathogenic disease especially threatening global apple production, is very difficult to control and manage.… read more here.

Keywords: thiosemicarbazone derivatives; thiosemicarbazone; acetyl benzylindoles; mechanism action ... See more keywords
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Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study

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recommendations! Published in 2019 at "Journal of the Iranian Chemical Society"

DOI: 10.1007/s13738-019-01592-8

Abstract: In this work, we report the synthesis, characterization, crystal structure, and thermal and antibacterial studies of a new nano-sized copper(I) thiosemicarbazone complex prepared by an ultrasonic bath assisted synthesis in an acetonitrile solution. Characterization of… read more here.

Keywords: crystal structure; thiosemicarbazone; characterization; synthesis ... See more keywords
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Complex formation reactions of gallium(III) and iron(III/II) with l-proline-thiosemicarbazone hybrids: A comparative study

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recommendations! Published in 2017 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2016.06.044

Abstract: Abstract Three new gallium(III) and iron(III) complexes with l -proline-thiosemicarbazone hybrids, namely [GaCl( l -Pro-FTSC–2H)]·0.7H2O·0.5CH3OH (1·0.7H2O·0.5CH3OH), [GaCl(dm- l -Pro-FTSC–2H)]·0.4H2O (2·0.4H2O) and [FeCl( l -Pro-FTDA–H)]Cl (3) were synthesised and comprehensively characterised by spectroscopic methods (1H, 13C… read more here.

Keywords: iii; iii iron; gallium iii; thiosemicarbazone ... See more keywords
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Experimental and theoretical studies of benzaldehyde thiosemicarbazone derivatives as corrosion inhibitors for mild steel in acid media

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recommendations! Published in 2019 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2018.09.048

Abstract: Abstract The inhibition behavior of three benzaldehyde thiosemicarbazone derivatives namely p-methoxybenzaldehyde thiosemicarbazone (MOBT), p-carboxybenzaldehyde thiosemicarbazone (COBT) and p-ethylbenzaldehyde thiosemicarbazone (EBT) for mild steel in 1.0 M HCl solution was studied systematically using gravimetric measurements, potentiodynamic polarization,… read more here.

Keywords: thiosemicarbazone; thiosemicarbazone derivatives; mild steel; benzaldehyde thiosemicarbazone ... See more keywords
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Spectroscopic characterization (IR and NMR), structural investigation, DFT study, and Hirshfeld surface analysis of two zinc(II) 2-acetylthiophenyl-thiosemicarbazone complexes

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recommendations! Published in 2020 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2020.129617

Abstract: ABSTRACT Zinc(II) complexes with 5-chloro-2-acetylthiophen-4-methyl-3-thiosemicarbazone and 5-methyl-2-acetylthiophen-4-methyl-3-thiosemicarbazone ligands were characterized by FT-IR, 1H NMR, single-crystal X-ray diffraction and Hirshfeld surface analysis. In both complexes, metal centers are four–coordinated in a distorted tetrahedral configuration by two… read more here.

Keywords: hirshfeld surface; dft; zinc; analysis ... See more keywords
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Synthesis, Characterization, and in Vitro Anticancer Activity of Copper and Zinc Bis(Thiosemicarbazone) Complexes.

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recommendations! Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.9b01281

Abstract: A series of eight bis(thiosemicarbazone) ligands and 16 of their respective copper(II) and zinc(II) complexes containing a combination of hydrogen, methyl, pyridyl, phenyl, and/or ethyl substituents at the diimine position of the ligand backbone were… read more here.

Keywords: bis thiosemicarbazone; copper; geometry; thiosemicarbazone ... See more keywords

Synthesis, structure, solution behavior, reactivity and biological evaluation of oxidovanadium(iv/v) thiosemicarbazone complexes.

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recommendations! Published in 2018 at "Dalton transactions"

DOI: 10.1039/c8dt01668b

Abstract: The synthesis and characterization of an oxidovanadium(iv) [VIVO(L)(acac)] (1) and of two dioxidovanadium(v) [VVO2(L')] (2) and [VVO2(L)] (2a) complexes of the Schiff base formed from the reaction of 4-(p-fluorophenyl) thiosemicarbazone with pyridine-2-aldehyde (HL) are described.… read more here.

Keywords: oxidovanadium; vvo2; thiosemicarbazone; vivo acac ... See more keywords
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Tetranuclear and dinuclear phenoxido bridged copper complexes based on unsymmetrical thiosemicarbazone ligands.

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recommendations! Published in 2018 at "Dalton transactions"

DOI: 10.1039/c8dt02452a

Abstract: We report on the synthesis of new dinucleating phenol-based "end-off" compartmental ligands HLMeH and HLMe2 bearing two different binding sites, one bis(2-methylpyridyl)aminomethyl (BPA) and one thiosemicarbazone (TSC) site, and their corresponding copper(ii) complexes 1t and… read more here.

Keywords: copper complexes; copper; thiosemicarbazone; spectroscopy ... See more keywords
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Synthesis, screening and biological activity of potent thiosemicarbazone compounds as a tyrosinase inhibitor

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recommendations! Published in 2019 at "New Journal of Chemistry"

DOI: 10.1039/c9nj02360g

Abstract: Inhibitors are designed based on coordination chemistry and catalytic circle of the tyrosinase, coordination atoms binds to copper and blocks enzyme activity, indicated that thiosemicarbazone species possess good potential as tyrosinase inhibitors. read more here.

Keywords: thiosemicarbazone; biological activity; activity; screening biological ... See more keywords