5-Nitrofuryl-Containing Thiosemicarbazone Gold(I) Compounds: Synthesis, Stability Studies, and Anticancer Activity.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300115
Abstract: This work describes the synthesis of four gold(I) [AuClL] compounds containing chloro and biologically active protonated thiosemicarbazones based on 5-nitrofuryl (L=HSTC). The stability of the compounds in dichloromethane, DMSO, and DMSO/culture media solutions was investigated… read more here.
Keywords: cell; stability; thiosemicarbazone; gold compounds ... See more keywords
Synthesis, structural, cytotoxic and pharmacokinetic evaluation of some thiosemicarbazone derivatives.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of biochemical and molecular toxicology"
DOI: 10.1002/jbt.22512
Abstract: Iron(III) and nickel(II) complexes bearing a thiosemicarbazone framework were synthesized by a one-pot synthesis method. The structures were characterized by elemental analysis, IR, 1 H NMR, APCI Mass, conductivity, magnetic moment measurements. Molecular and crystal structures… read more here.
Keywords: pharmacokinetic evaluation; cytotoxic pharmacokinetic; synthesis structural; evaluation thiosemicarbazone ... See more keywords
Natural products in crop protection: thiosemicarbazone derivatives of 3-acetyl-N-benzylindoles as antifungal agents and their mechanism of action.
Sign Up to like & getrecommendations! Published in 2023 at "Pest management science"
DOI: 10.1002/ps.7457
Abstract: BACKGROUND Phytopathogenic fungi can cause a direct loss in economic value of agriculture. Especially Valsa mali Miyabe et Yamada, a devastating phytopathogenic disease especially threatening global apple production, is very difficult to control and manage.… read more here.
Keywords: thiosemicarbazone derivatives; thiosemicarbazone; acetyl benzylindoles; mechanism action ... See more keywords
A Flexible Asymmetric Supercapacitor with High‐Performance and Long‐Lifetime: Fabrication of Nanoworm‐Like‐Structured Electrodes Based on Polypyrrole‐Thiosemicarbazone Complex
Sign Up to like & getrecommendations! Published in 2024 at "Small Methods"
DOI: 10.1002/smtd.202401140
Abstract: A thiosemicarbazone‐based iron(III) complex is prepared and used in the preparation of a supercapacitor electrode material. This electrode is produced by a solvothermal reaction of polypyrrole and the complex on carbon felt. The characterization of… read more here.
Keywords: thiosemicarbazone; asymmetric supercapacitor; supercapacitor; performance ... See more keywords
Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the Iranian Chemical Society"
DOI: 10.1007/s13738-019-01592-8
Abstract: In this work, we report the synthesis, characterization, crystal structure, and thermal and antibacterial studies of a new nano-sized copper(I) thiosemicarbazone complex prepared by an ultrasonic bath assisted synthesis in an acetonitrile solution. Characterization of… read more here.
Keywords: crystal structure; thiosemicarbazone; characterization; synthesis ... See more keywords
Complex formation reactions of gallium(III) and iron(III/II) with l-proline-thiosemicarbazone hybrids: A comparative study
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.06.044
Abstract: Abstract Three new gallium(III) and iron(III) complexes with l -proline-thiosemicarbazone hybrids, namely [GaCl( l -Pro-FTSC–2H)]·0.7H2O·0.5CH3OH (1·0.7H2O·0.5CH3OH), [GaCl(dm- l -Pro-FTSC–2H)]·0.4H2O (2·0.4H2O) and [FeCl( l -Pro-FTDA–H)]Cl (3) were synthesised and comprehensively characterised by spectroscopic methods (1H, 13C… read more here.
Keywords: iii; iii iron; gallium iii; thiosemicarbazone ... See more keywords
Experimental and theoretical studies of benzaldehyde thiosemicarbazone derivatives as corrosion inhibitors for mild steel in acid media
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.09.048
Abstract: Abstract The inhibition behavior of three benzaldehyde thiosemicarbazone derivatives namely p-methoxybenzaldehyde thiosemicarbazone (MOBT), p-carboxybenzaldehyde thiosemicarbazone (COBT) and p-ethylbenzaldehyde thiosemicarbazone (EBT) for mild steel in 1.0 M HCl solution was studied systematically using gravimetric measurements, potentiodynamic polarization,… read more here.
Keywords: thiosemicarbazone; thiosemicarbazone derivatives; mild steel; benzaldehyde thiosemicarbazone ... See more keywords
Spectroscopic characterization (IR and NMR), structural investigation, DFT study, and Hirshfeld surface analysis of two zinc(II) 2-acetylthiophenyl-thiosemicarbazone complexes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129617
Abstract: ABSTRACT Zinc(II) complexes with 5-chloro-2-acetylthiophen-4-methyl-3-thiosemicarbazone and 5-methyl-2-acetylthiophen-4-methyl-3-thiosemicarbazone ligands were characterized by FT-IR, 1H NMR, single-crystal X-ray diffraction and Hirshfeld surface analysis. In both complexes, metal centers are four–coordinated in a distorted tetrahedral configuration by two… read more here.
Keywords: hirshfeld surface; dft; zinc; analysis ... See more keywords
Bis-thiosemicarbazone Ligands as Candidates for Radioantimony(III) Chelation for Use in Theranostic Applications.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04268
Abstract: Thermodynamic stabilization of antimony complexes against hydrolysis in biological environments is critical for the effective delivery of theranostic radionuclides such as 117Sb and 119Sb in nuclear medicine. We report a series of Sb(III) complexes formed… read more here.
Keywords: candidates radioantimony; ligands candidates; iii; thiosemicarbazone ... See more keywords
Synthesis, Characterization, and in Vitro Anticancer Activity of Copper and Zinc Bis(Thiosemicarbazone) Complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01281
Abstract: A series of eight bis(thiosemicarbazone) ligands and 16 of their respective copper(II) and zinc(II) complexes containing a combination of hydrogen, methyl, pyridyl, phenyl, and/or ethyl substituents at the diimine position of the ligand backbone were… read more here.
Keywords: bis thiosemicarbazone; copper; geometry; thiosemicarbazone ... See more keywords
Thiosemicarbazone Mixed-Valence Cu(I/II) Complex against Lung Adenocarcinoma Cells through Multiple Pathways Involving Cuproptosis.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of medicinal chemistry"
DOI: 10.1021/acs.jmedchem.4c00257
Abstract: Induction of cuproptosis and targeting of multiple signaling pathways show promising applications in tumor therapy. In this study, we synthesized two thiosemicarbazone-copper complexes ([CuII(L)Cl] 1 and [CuII2CuI(L)2Cl3] 2, where HL is the (E)-N-methyl-2-(phenyl(pyridin-2-yl)methylene ligand), to… read more here.
Keywords: cancer; copper complexes; lung; thiosemicarbazone ... See more keywords