Photoactive Metal-Organic Frameworks for the Selective Synthesis of Thioethers: Coupled with Phosphine to Modulate Thiyl Radical Generation.
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DOI: 10.1021/acs.inorgchem.1c00642
Abstract: Metal-organic framework (MOF) materials are intriguing photocatalysts to trigger radical-mediated chemical transformations. We report herein the synthesis and characterization of a series of isomorphic MOFs which show a novel structure, wide visible-light absorption, high chemical… read more here.
Keywords: thiyl; thiyl radical; metal organic; generation ... See more keywords