A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium-Carbon Bonds.
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DOI: 10.1021/jacs.7b02356
Abstract: A new thorium monoalkyl complex, Th(CH2SiMe3)(L3) (L = MeC(NiPr)2) (2), undergoes insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th(ECH2SiMe3)(L3) (E = S, SS, Se, Te; 5-8). Complex 6 represents the… read more here.
Keywords: thorium chalcogenolate; insertion; thorium; atom insertion ... See more keywords