Dioximes of 1,6-heptanediones from acetylene and ketones: only three atom-economic steps
Sign Up to like & getrecommendations! Published in 2018 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2018.03.010
Abstract: 2-Acetyl-3,4-dihydropyrans, synthesized from acetylene and ketones in two steps, react with hydroxylamine to afford 5-hydroxy-1,6-heptanedione dioximes (E,E-isomers) in 72–96% yields. read more here.
Keywords: acetylene ketones; three atom; ketones three; dioximes heptanediones ... See more keywords
α-Nitrosostyrenes as Three-Atom Units for the (3+1) Cyclization Reaction: Facile Access to 2,3-Dihydrodiazete N-Oxides and Their Diversified Synthetic Conversions.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00024
Abstract: An unprecedented (3+1) cyclization of α-nitrosostyrenes, generated in situ from α-bromooximes, and N-tosyloxycarbamates was developed, which enables the synthesis of a range of structurally unique and hitherto unexplored 2,3-dihydrodiazete N-oxides in moderate to high yields.… read more here.
Keywords: units cyclization; nitrosostyrenes three; dihydrodiazete oxides; atom units ... See more keywords
A gateway towards non-collinear spin processing using three-atom magnets with strong substrate coupling
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DOI: 10.1038/s41467-017-00506-7
Abstract: A cluster of a few magnetic atoms on the surface of a nonmagnetic substrate is one suitable realization of a bit for spin-based information technology. The prevalent approach to achieve magnetic stability is decoupling the… read more here.
Keywords: three atom; non collinear; spin; atom magnets ... See more keywords
Tailoring of Three-Atom Metal Cluster Catalysts for Ammonia Synthesis
Sign Up to like & getrecommendations! Published in 2023 at "Catalysts"
DOI: 10.3390/catal13050869
Abstract: Electrocatalytic nitrogen reduction reaction (NRR) can realize the green production of ammonia while developing electrocatalysts with high selectivity and ability is still an ongoing challenge. Two-dimensional (2D) graphitic carbon nitride (CN) frameworks can provide abundant… read more here.
Keywords: tailoring three; ammonia synthesis; synthesis; cluster ... See more keywords